Synthesis of some metallophthalocyanines with dimethyl 5-(phenoxy)-isophthalate substituents and evaluation of their antioxidant-antibacterial activities

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dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorKaratas, Ceyhun
dc.contributor.authorOzdemir, Sadin
dc.date.accessioned2024-12-24T19:27:44Z
dc.date.available2024-12-24T19:27:44Z
dc.date.issued2015
dc.departmentSiirt Üniversitesi
dc.description.abstractThe synthesis, characterization, spectral, antioxidant and antibacterial properties of dimethyl 5-(phenoxy)-isophthalate substituted Zinc, Cobalt, Copper, and Nickel phthalocyanines are reported. The novel compounds have been characterized by using electronic absorption, nuclear magnetic resonance spectroscopy, infrared, elemental analysis and mass spectrometry. The antioxidant and antibacterial activities of newly synthesized phthalocyanines and its starting material are tested. The DPPH free radical scavenging ability of phthalocyanine Co(II) and Zn(II) complexes on DPPH are 44.8% and 40.1% at 100 mg/L concentration, respectively. The phthalocyanine Co(II) and Cu(II) complexes show very strong ferrous ion chelating activity of 91.2% and 89.3% at concentration of 100 mg/L, respectively. Compound 3 displays strong reducing power like alpha-tocopherol. Antibacterial activities of phthalocyanine Co(II) and Amikacin (30 mu g/disk) against Micrococcus luteus (ATCC 9341) are 16 mm in diameter. (C) 2014 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.saa.2014.06.139
dc.identifier.endpage24
dc.identifier.issn1386-1425
dc.identifier.pmid25036645
dc.identifier.scopus2-s2.0-84904572662
dc.identifier.scopusqualityQ1
dc.identifier.startpage20
dc.identifier.urihttps://doi.org/10.1016/j.saa.2014.06.139
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6767
dc.identifier.volume135
dc.identifier.wosWOS:000343337700004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectSynthesis
dc.subjectPhthalocyanine
dc.subjectCharacterization
dc.subjectAntioxidant
dc.subjectAntibacterial
dc.subjectIsophthalate
dc.titleSynthesis of some metallophthalocyanines with dimethyl 5-(phenoxy)-isophthalate substituents and evaluation of their antioxidant-antibacterial activities
dc.typeArticle

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