Cu(II), Co(II), Ni(II), Mn(II), and Fe(II) metal complexes containing N,N?-(3,4-diaminobenzophenon)-3,5-But2-salicylaldimine ligand: Synthesis, structural characterization, thermal properties, electrochemistry, and spectroelectrochemistry

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dc.authoridDurgun, Mustafa/0000-0003-3012-7582
dc.authoridKILIC, Ahmet/0000-0001-9073-4339
dc.authoridyilmaz, ismail/0000-0002-5046-7456
dc.contributor.authorTas, E.
dc.contributor.authorKilic, A.
dc.contributor.authorDurgun, M.
dc.contributor.authorKupecik, L.
dc.contributor.authorYilmaz, I.
dc.contributor.authorArslan, S.
dc.date.accessioned2024-12-24T19:27:44Z
dc.date.available2024-12-24T19:27:44Z
dc.date.issued2010
dc.departmentSiirt Üniversitesi
dc.description.abstractThe synthesis, structure, spectroscopic and electro-spectrochemical properties of steric hindered Schiff-base ligand [N,N'-(3,4-benzophenon)-3,5-Bu-2(t)-salicylaldimine (LH2)] and its mononuclear Cu(II), Co(II), Ni(II), Mn(II) and Fe(II) complexes are described in this work. The new dissymmetric steric hindered Schiff-base ligand containing a donor set of NONO was prepared through reaction of 3,4-diaminobenzophenon with 3,5-Bu-2(t)-salicylaldehyde. Certain metal complexes of this ligand were synthesized by treating an ethanolic solution of the ligand with an equimolar amount of metal salts. The ligand and its complexes were characterized by FT-IR, UV-vis, H-1 NMR, elemental analysis, molar conductivity and thermal analysis methods in addition to magnetic susceptibility, electrochemistry and spectroelectrochemistry techniques. The tetradentate and mononuclear metal complexes were obtained by reacting N,N'-(3,4-benzophenon)-3,5-Bu-2(t)-salicylaldimine (LH2) with some metal acetate in a 1:1 mole ratio. The molar conductance data suggest metal complexes to be non-electrolytes. (C) 2009 Elsevier B.V. All rights reserved.
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [106T085]; Harran University Research Fund (HUBAK) [752]
dc.description.sponsorshipThis work have been supported, in part, by the Technological and Scientific Research Council of Turkey TUBITAK (TBAG Project No.: 106T085) and by the Harran University Research Fund (HUBAK, Grant No.: 752) is gratefully acknowledged.
dc.identifier.doi10.1016/j.saa.2009.12.002
dc.identifier.endpage818
dc.identifier.issn1386-1425
dc.identifier.issue2
dc.identifier.pmid20036615
dc.identifier.scopus2-s2.0-73749083745
dc.identifier.scopusqualityQ1
dc.identifier.startpage811
dc.identifier.urihttps://doi.org/10.1016/j.saa.2009.12.002
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6765
dc.identifier.volume75
dc.identifier.wosWOS:000274591200049
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectSynthesis
dc.subjectSchiff bases
dc.subjectMetal complexes
dc.subjectThermal properties
dc.subjectElectrochemistry
dc.subjectSpectroelectrochemistry
dc.titleCu(II), Co(II), Ni(II), Mn(II), and Fe(II) metal complexes containing N,N?-(3,4-diaminobenzophenon)-3,5-But2-salicylaldimine ligand: Synthesis, structural characterization, thermal properties, electrochemistry, and spectroelectrochemistry
dc.typeArticle

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