The Novel Polymethacrylate Based Hydrophilic Stationary Phase for Ion Chromatography

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dc.authoridSAMATYA, SABA/0000-0002-9927-2270
dc.contributor.authorOlmez, Saba Samatya
dc.contributor.authorKokden, Didem
dc.contributor.authorTuncel, Ali
dc.date.accessioned2024-12-24T19:28:29Z
dc.date.available2024-12-24T19:28:29Z
dc.date.issued2023
dc.departmentSiirt Üniversitesi
dc.description.abstractIon chromatography is widely used as a useful and powerful tool for the analysis of anionic and cationic components found in waters and aqueous media. The performance and selectivity of ion chromatography are based on the stationary phase column packed material. In this study, it is aimed to develop new column material with quaternary ammonium functional group based on monodisperse polymeric particles for ion chromatography and to investigate their chromatographic performance. For the analysis of inorganic anions by ion chromatography, new stationary phases macroporous monodisperse particles based on 3-chloro-2-hydroxy propylmethacrylate-co-ethylene dimethacrylate are obtained as column packing material. 3-chloro-2-hydroxy propylmethacrylate and ethylene glycol dimethacrylate are transformed to porous monodisperse particle form by using glycidyl methacrylate as the seed latex and ethyl benzene as the porogen solvent via micro-suspension polymerization technique. Then macroporous monodisperse particles surface is functionalized by triethylamine so strong anion exchange is obtained for ion chromatography packing material. A series of stationary phases prepared from polymer particles containing different amounts of porogen solvent were tested. The results show that column packing material is successful to separate inorganic anions mixture such as F-, Cl-, NO2-, Br-, NO3- by using the carbonate and bicarbonate solutions as mobile phases.
dc.identifier.doi10.1093/chromsci/bmac034
dc.identifier.endpage417
dc.identifier.issn0021-9665
dc.identifier.issn1945-239X
dc.identifier.issue5
dc.identifier.pmid35428883
dc.identifier.scopus2-s2.0-85160967917
dc.identifier.scopusqualityQ3
dc.identifier.startpage410
dc.identifier.urihttps://doi.org/10.1093/chromsci/bmac034
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7086
dc.identifier.volume61
dc.identifier.wosWOS:000784525100001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherOxford Univ Press Inc
dc.relation.ispartofJournal of Chromatographic Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.titleThe Novel Polymethacrylate Based Hydrophilic Stationary Phase for Ion Chromatography
dc.typeArticle

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