Synthesis, Aggregation, Antioxidant and DNA-Binding Properties of Metallophthalocyanines Bearing 5-Tert-butyl-2-hydroxyphenoxy groups

dc.authoridhttps://orcid.org/0000-0002-5505-2700en_US
dc.contributor.authorAğırtaş, Salih
dc.contributor.authorCabir, Beyza
dc.contributor.authorÖzdemir, Sadin
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorAslantaş, Ali
dc.date.accessioned2019-12-23T07:54:19Z
dc.date.available2019-12-23T07:54:19Z
dc.date.issued2017en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstractIn this study, the synthesis and characterization of new substituted metallophthalocyanines are described. A new phthalonitrile, 4-(5-tert-butyl-2-hydroxyphenoxy)-5-chlorophthalonitrile (3) was prepared. New compounds were characterized by UV–Vis, IR, 1HNMR, and elemental analysis. The aggregation behavior of the cobalt (II), magnesium (II) and copper (II) phthalocyanines were studied in tetrahydrofuran and in known concentration ranges. The antioxidant activities of compounds were evaluated. Their radical-scavenging capacity, metal chelating activity and reducing power was fully studied. The compound 3 showed 100% chelating activity as EDTA at concentration 50 mg/L. The DNA interaction of copper (II) phthalocyanine compound (6) was studied using UV/Vis titration, gel electrophoresis, cyclic voltammetry. The results indicated that compound 6 interacts with CT-DNA via intercalation binding mode.en_US
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dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-23T07:54:19Z (GMT) No. of bitstreams: 1 A31.pdf: 7538256 bytes, checksum: 5a26578a832d19b0e8a45954d6a36243 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-23T07:54:19Z (GMT). No. of bitstreams: 1 A31.pdf: 7538256 bytes, checksum: 5a26578a832d19b0e8a45954d6a36243 (MD5) Previous issue date: 2017en
dc.identifier.citationMehmet Salih, A. Beyza, C. Sadin, O. Veysi, O. Ali, A. (2017). Synthesis, Aggregation, Antioxidant and DNA-Binding Properties of Metallophthalocyanines Bearing 5-Tert-butyl-2-hydroxyphenoxy groups : Chemistry Selecten_US
dc.identifier.endpage11357en_US
dc.identifier.scopus2-s2.0-85041863526
dc.identifier.scopusqualityQ3
dc.identifier.startpage11352en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2356
dc.identifier.volume2en_US
dc.identifier.wosWOS:000417743100059
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorOkumuş, Veysi
dc.language.isotren_US
dc.publisherChemistry Selecten_US
dc.relation.ispartofChemistry Select
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKG_20241224
dc.subjectAggregationen_US
dc.subjectAntioxidanten_US
dc.subjectDNA Bindingen_US
dc.subjectPhthalocyaninesen_US
dc.subjectSynthesisen_US
dc.titleSynthesis, Aggregation, Antioxidant and DNA-Binding Properties of Metallophthalocyanines Bearing 5-Tert-butyl-2-hydroxyphenoxy groupsen_US
dc.typeArticleen_US

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