Effects of plasma treatment, La content and temperature on the La-Ni-Mo-B catalysts for hydrogen production from NaBH4 hydrolysis

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dc.authoridBalbay, Asim/0000-0003-1052-5903
dc.contributor.authorSahin, Omer
dc.contributor.authorEkinci, Arzu
dc.contributor.authorBalbay, Asim
dc.contributor.authorSaka, Cafer
dc.date.accessioned2024-12-24T19:28:05Z
dc.date.available2024-12-24T19:28:05Z
dc.date.issued2017
dc.departmentSiirt Üniversitesi
dc.description.abstractLa-Ni-Mo-B catalysts with 0.15, 0.21 and 0.30-mol La molar ratio are prepared by a mixing method followed by a plasma treatment, characterised and investigated for hydrogen production via sodium borohydride hydrolysis. XRD, SEM, Brunauer-Emmett-Teller and FTIR techniques are used for characterising the catalysts. The hydrogen generation rate at 60 degrees C compared to 30 degrees C using La-Ni-Mo-B under the same conditions is significantly different. The effect of temperature, plasma application time and different plasma gases on hydrogen generation from NaBH4 hydrolysis reaction using La-0.21-Ni-Mo-B catalyst is investigated. It was found that the plasma-treated catalysts exhibited low activation energy for zero order (58 kJ mol(-1)).
dc.description.sponsorshipResearch Foundation of Siirt University [2013-SIU-MUH-M5]
dc.description.sponsorshipThe authors are grateful to the Research Foundation of Siirt University for financial support under Project 2013-SIU-MUH-M5.
dc.identifier.doi10.1080/02670844.2016.1271764
dc.identifier.endpage505
dc.identifier.issn0267-0844
dc.identifier.issn1743-2944
dc.identifier.issue7
dc.identifier.scopus2-s2.0-85010635798
dc.identifier.scopusqualityQ2
dc.identifier.startpage499
dc.identifier.urihttps://doi.org/10.1080/02670844.2016.1271764
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6919
dc.identifier.volume33
dc.identifier.wosWOS:000399657700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofSurface Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPlasma
dc.subjectsurface
dc.subjectmodification
dc.subjectlantanium
dc.subjectsodium borohydride
dc.subjecttemperature
dc.subjectLa-Ni-mo-B
dc.titleEffects of plasma treatment, La content and temperature on the La-Ni-Mo-B catalysts for hydrogen production from NaBH4 hydrolysis
dc.typeArticle

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