Synthesis of Some Novel Phthalocyanines with Methyl 2-(oxy)-2,2-diphenylacetate Substituents, Evaluation of Their Antioxidant- Antibacterial Activities and Electronic Properties

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dc.authoridOkumus, Veysi/0000-0002-5505-2700
dc.authoridGumus, Selcuk/0000-0002-8628-8943
dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorKaratas, Ceyhun
dc.contributor.authorGumus, Selcuk
dc.contributor.authorOkumus, Veysi
dc.date.accessioned2024-12-24T19:24:23Z
dc.date.available2024-12-24T19:24:23Z
dc.date.issued2015
dc.departmentSiirt Üniversitesi
dc.description.abstractThe synthesis, characterization, spectral, antioxidant, and antibacterial properties of methyl 2-(oxy)-2,2-diphenylacetate substituted metallophthalocyanines (4-7) are reported. A novel phthalonitrile, methyl 2-(2,3-dicyanophenoxy)-2,2-diphenylacetate (3) was prepared and characterized. The new compounds were characterized by using electronic absorption spectroscopy, nuclear magnetic resonance spectroscopy, infrared spectroscopy, and elemental analysis. All compounds were tested for their antioxidant activity by using 2,2-diphenyl-1-picrylhydrazyl radical scavenging ability, metal chelating, and reducing power. Furthermore, these compounds were screened for their in vitro growth inhibiting activity by disc diffusion method against four gram positive and two gram negative bacteria. The electronic data of the new compounds were obtained by computational calculations at B3LYP/6-31G(d,p) level of theory.
dc.identifier.doi10.1002/zaac.201400445
dc.identifier.endpage447
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue2
dc.identifier.scopus2-s2.0-84922824025
dc.identifier.scopusqualityQ3
dc.identifier.startpage442
dc.identifier.urihttps://doi.org/10.1002/zaac.201400445
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5955
dc.identifier.volume641
dc.identifier.wosWOS:000351444500050
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241222
dc.subjectSynthesis
dc.subjectCharacterization
dc.subjectPhthalocyanines
dc.subjectAggregation
dc.subjectAntioxidant properties
dc.subjectAntibacterial properties
dc.titleSynthesis of Some Novel Phthalocyanines with Methyl 2-(oxy)-2,2-diphenylacetate Substituents, Evaluation of Their Antioxidant- Antibacterial Activities and Electronic Properties
dc.typeArticle

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