Effect of Al2O3-supported Cu-Schiff base complex as a catalyst for hydrogen generation in NaBH4 hydrolysis

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dc.contributor.authorKilinc, Dilek
dc.date.accessioned2024-12-24T19:28:25Z
dc.date.available2024-12-24T19:28:25Z
dc.date.issued2018
dc.departmentSiirt Üniversitesi
dc.description.abstractCu-Schiff base complex which we previously synthesized (Kilinc et al., 2012) is supported on Al2O3. The prepared catalyst is characterized by using SEM, XRD, BET, and FT-IR methods. And Al2O3-supported complex is used as a catalyst in NaBH4 hydrolysis reaction for hydrogen generation. NaBH4 hydrolysis reactions are investigated depending on the concentration of NaBH4 and NaOH, temperature, percentage of Cu complex, and amount of catalyst. Maximum reaction rates are 44,453.33 and 57,410.00 mL H-2/g.cat.min at 30 degrees C and 50 degrees C, respectively. The activation energy of NaBH4 hydrolysis reaction is found as 225,775 kJ(.)mol(-1). All the experimental results and literature comparisons show that Al2O3-supported Cu-Schiff base complex is a very effective catalyst in NaBH4 hydrolysis for H-2 generation.
dc.identifier.doi10.1080/15567036.2018.1463318
dc.identifier.endpage885
dc.identifier.issn1556-7036
dc.identifier.issn1556-7230
dc.identifier.issue7
dc.identifier.scopus2-s2.0-85045845788
dc.identifier.scopusqualityQ1
dc.identifier.startpage873
dc.identifier.urihttps://doi.org/10.1080/15567036.2018.1463318
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7036
dc.identifier.volume40
dc.identifier.wosWOS:000431543000014
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofEnergy Sources Part A-Recovery Utilization and Environmental Effects
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectComplex
dc.subjecthydrogen generation
dc.subjecthydrolysis
dc.subjectNaBH4
dc.subjectSchiff base
dc.titleEffect of Al2O3-supported Cu-Schiff base complex as a catalyst for hydrogen generation in NaBH4 hydrolysis
dc.typeArticle

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