Hydrogen generation from catalytic hydrolysis of sodium borohydride by a novel Co(II)-Cu(II) based complex catalyst

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dc.authoridSAKA, Cafer/0000-0003-2534-5921
dc.authoridSAHIN, Omer/0000-0003-4575-3762
dc.contributor.authorKilinc, Dilek
dc.contributor.authorSaka, Cafer
dc.contributor.authorSahin, Omer
dc.date.accessioned2024-12-24T19:27:28Z
dc.date.available2024-12-24T19:27:28Z
dc.date.issued2012
dc.departmentSiirt Üniversitesi
dc.description.abstractIn the present work, Co(II)-Cu(II) supported salicylaldimine derivatives complex catalysts and their mixtures are tested for hydrogen generation from the hydrolysis reaction of sodium borohydride (NaBH4). The hydrolysis of NaBH4 with Co(II)-Cu(II) supported complex catalysts is investigated depending on the Co(II)-Cu(II) ratio, NaBH4 concentration, NaOH concentration, temperature and catalyst amount. The results suggested that the optimal mixture percentage of Co(II)-Cu(II) catalyst is 40:60. The obtained complex catalysts are characterized by XRD, FT-IR and SEM techniques and evaluated for their activity for the hydrogen generation from the hydrolysis reaction of NaBH4. (C) 2012 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.jpowsour.2012.06.018
dc.identifier.endpage261
dc.identifier.issn0378-7753
dc.identifier.issn1873-2755
dc.identifier.scopus2-s2.0-84862997765
dc.identifier.scopusqualityQ1
dc.identifier.startpage256
dc.identifier.urihttps://doi.org/10.1016/j.jpowsour.2012.06.018
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6641
dc.identifier.volume217
dc.identifier.wosWOS:000308782200039
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Power Sources
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectCopper-Cobalt complex catalysts
dc.subjectSodium borohydride hydrolysis
dc.subjectHydrogen generation
dc.titleHydrogen generation from catalytic hydrolysis of sodium borohydride by a novel Co(II)-Cu(II) based complex catalyst
dc.typeArticle

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