Synthesis, characterization and mass spectral studies on acrocyclic schiff base complexes of Pb(II), Zn(II) and La(III)

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dc.authoridIlhan, Salih/0000-0003-0779-2744
dc.contributor.authorIlhan, Salih
dc.date.accessioned2024-12-24T19:29:37Z
dc.date.available2024-12-24T19:29:37Z
dc.date.issued2010
dc.departmentSiirt Üniversitesi
dc.description.abstractSix new macrocyclic complexes were synthesized by template reaction of (+/-)-1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane or 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and their structures were proposed on the basis of elemental analysis, FT-IR, UV-Vis, molar conductivity measurements, H-1 NMR and mass spectra. The metals to ligand molar ratios of the complexes were found to be 1: 1. The complexes are 1: 2 electrolytes for Pb(II) and Zn(II) complexes and 1: 3 electrolytes for La(III) as shown by their molar conductivities (I >(m)) in DMSO at 10(-3) mol L-1. Due to the existence of free ions in these complexes, such complexes are electrically conductive. The configurations of La(III) and Zn(II) complexes were proposed to probably octahedral.
dc.identifier.doi10.1134/S0036023610040157
dc.identifier.endpage593
dc.identifier.issn0036-0236
dc.identifier.issn1531-8613
dc.identifier.issue4
dc.identifier.scopus2-s2.0-77952152447
dc.identifier.scopusqualityQ2
dc.identifier.startpage583
dc.identifier.urihttps://doi.org/10.1134/S0036023610040157
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7177
dc.identifier.volume55
dc.identifier.wosWOS:000277345800007
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofRussian Journal of Inorganic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.titleSynthesis, characterization and mass spectral studies on acrocyclic schiff base complexes of Pb(II), Zn(II) and La(III)
dc.typeArticle

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