Metal-free catalyst fabrication by incorporating oxygen groups on the surface of the carbonaceous sample and efficient hydrogen production from NaBH4 methanolysis

Basit Öğe Kaydı
dc.authoridSAKA, Cafer/0000-0003-2534-5921
dc.contributor.authorSaka, Cafer
dc.contributor.authorBalbay, Asim
dc.date.accessioned2024-12-24T19:27:16Z
dc.date.available2024-12-24T19:27:16Z
dc.date.issued2022
dc.departmentSiirt Üniversitesi
dc.description.abstractIn the present study, metal-free catalysts for efficient H-2 generation from NaBH4 methanolysis was produced for the first time from apricot kernel shells with two-step activation. The first stage of the two-stage activation includes the production of activated carbon with the KOH agent (AKOH), and the second stage includes hydrothermally HNO3 activation with oxygen doping (O doped AKOH + N). The hydrogen production rate (HGR) and the activation energy (Ea) of the reaction with the obtained metal-free catalyst (10 mg) were determined as 14,444 ml min(-1) g(-1) and 7.86 kJ mol(-1), respectively. The structural and physical-chemical properties of these catalysts were characterized by XRD (X-ray diffraction), SEM (scanning electron microscopy), elemental CHNS analysis, FT-IR (Fourier transform infrared spectroscopy), and nitrogen adsorption analysis. Also, the reusability results of this metal-free catalyst for H-2 production are promising. (C) 2021 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.
dc.description.sponsorshipSiirt University Scientific Research Unit [2020-S_IUSYO-001]
dc.description.sponsorshipSiirt University Scientific Research Unit supported this study (2020-S_IUSYO-001).
dc.identifier.doi10.1016/j.ijhydene.2021.12.070
dc.identifier.endpage7251
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue11
dc.identifier.scopus2-s2.0-85122099922
dc.identifier.scopusqualityQ1
dc.identifier.startpage7242
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2021.12.070
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6571
dc.identifier.volume47
dc.identifier.wosWOS:000748997900005
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectApricot kernel shells
dc.subjectMetal-free catalyst
dc.subjectOxygen doping
dc.subjectSodium borohydride methanolysis
dc.subjectHydrogen
dc.titleMetal-free catalyst fabrication by incorporating oxygen groups on the surface of the carbonaceous sample and efficient hydrogen production from NaBH4 methanolysis
dc.typeArticle

Dosyalar

Koleksiyon

WOS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu