Synthesis and spectral studies of macrocyclic Pb(II), Zn(II) and La(III) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives

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dc.authoridIlhan, Salih/0000-0003-0779-2744
dc.contributor.authorIlhan, Salih
dc.date.accessioned2024-12-24T19:31:00Z
dc.date.available2024-12-24T19:31:00Z
dc.date.issued2010
dc.departmentSiirt Üniversitesi
dc.description.abstractSix new macrocyclic complexes are synthesised by template reaction of 1,4-bis(3-aminopropoxy)butane with metal nitrate and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane or 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and their structures are proposed on the basis of elemental analysis, FT-IR, UV-Vis, molar conductivity measurements, H-1 NMR and mass spectra. The complexes are 1: 2 electrolytes for Pb(II), Zn(II) complexes and 1:3 electrolytes for La(III) as shown by their molar conductivities (Lambda(m)) in DMSO at 10(-3) mol L-1. The configurations of La(III) and Zn(II) complexes are proposed to probably octahedral.
dc.identifier.doi10.3184/030823409X12609007112282
dc.identifier.endpage4
dc.identifier.issn1747-5198
dc.identifier.issn2047-6507
dc.identifier.issue1
dc.identifier.scopus2-s2.0-77949404344
dc.identifier.scopusqualityQ3
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.3184/030823409X12609007112282
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7766
dc.identifier.wosWOS:000275412500001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSage Publications Ltd
dc.relation.ispartofJournal of Chemical Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectmacrocyclic Schiff base
dc.subjectmacrocyclic complexes
dc.subject1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane
dc.subject1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and 1,4-bis(3-aminopropoxy) butane
dc.titleSynthesis and spectral studies of macrocyclic Pb(II), Zn(II) and La(III) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives
dc.typeArticle

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