New water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties

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dc.authoridGumus, Selcuk/0000-0002-8628-8943
dc.authoridCELEBI, METIN/0000-0003-1475-8878
dc.authoridOkumus, Veysi/0000-0002-5505-2700
dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorCelebi, Metin
dc.contributor.authorGumus, Selcuk
dc.contributor.authorOzdemir, Sadin
dc.contributor.authorOkumus, Veysi
dc.date.accessioned2024-12-24T19:27:01Z
dc.date.available2024-12-24T19:27:01Z
dc.date.issued2013
dc.departmentSiirt Üniversitesi
dc.description.abstractNovel substituted phthalonitrile derivatives were obtained by the reaction of 2-(4-hydroxyphenylazo) benzoic acid and 4,5-dichloro-1,2-dicyanobenzene, or 4-nitrophthalonitrile. Peripherally phenoxy phenyl diazenyl benzoic acid substituted zinc (II) phthalocyanine complexes, and their sodium salts were synthesized and characterized for the first time. The newly synthesized phthalocyanine complexes show excellent solubility in water. The aggregation investigations carried out in different concentrations indicate that phenoxy phenyl diazenyl benzoic acid-substituted phthalocyanine compounds do not have any aggregation behavior for the concentration range of 7.00 x 10(-5)-4.38 x 10(-6) M in DMF. The antioxidant activities of DMF solution of compounds were analyzed through radical scavenging, and chelating ability to Fe2+ cation. Additionally, new compounds did not show any antibacterial activity against some selected bacteria cultures. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6-31G(d,p) level in order to obtain information about the 3D geometries and electronic structure. (C) 2013 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipYuzuncu Yil University [2011-FED-B012]
dc.description.sponsorshipThis study was supported by the Research Fund of Yuzuncu Yil University (2011-FED-B012).
dc.identifier.doi10.1016/j.dyepig.2013.05.019
dc.identifier.endpage431
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.issue2
dc.identifier.scopus2-s2.0-84879466748
dc.identifier.scopusqualityQ1
dc.identifier.startpage423
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2013.05.019
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6467
dc.identifier.volume99
dc.identifier.wosWOS:000323095000022
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPhthalocyanines
dc.subjectPhthalonitrile derivatives
dc.subjectAntioxidant activities
dc.subjectAggregation
dc.subjectSolubility
dc.subjectDFT
dc.titleNew water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties
dc.typeArticle

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