Bimetallic Co–Ni based complex catalyst for hydrogen production by catalytic hydrolysis of sodium borohydride with an alternative approach

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dc.contributor.authorŞahin, Ömer
dc.contributor.authorKılınç, Dilek
dc.contributor.authorSaka, Cafer
dc.date.accessioned2019-11-13T09:32:18Z
dc.date.available2019-11-13T09:32:18Z
dc.date.issued2016
dc.departmentBelirleneceken_US
dc.description.abstractHydrogen is a clean energy carrier and is expected to be one of the main energy sources in the 21st century. The basic aim of this study is to develop a feasible new catalyst system for the hydrogen generation by catalytic hydrolysis of NaBH4. The method is an alternative approach for the hydrogen production with metal catalysts. Ni–Co bimetallic complex catalysts with different Co–Ni contents were derived from 4-4'-methylene bis (2,6-diethyl)aniline-3,5-di-tert-butylsalisilaldimin ligand and their catalytic performances were investigated with hydrogen generation by catalytic hydrolysis of NaBH4. Experimental results showed that the Co–Ni contained catalysts exhibited much higher activity than the monometallic complex catalyst. The optimal mixture percentage of Co–Ni complex catalyst was 80:20. It was found that a combination of 2.5 wt% NaBH4 solution concentration and 5 wt% NaOH yields the highest performance for the hydrogen generation. The catalysts were characterized by XRD, FT-IR and SEM techniques.en_US
dc.identifier.scopus2-s2.0-84997113423
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://hdl.handle.net/20.500.12604/1460
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier-Journal of the Energy Instituteen_US
dc.relation.publicationcategoryUluslararası Hakemli Dergi Makalesien_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKG_20241224
dc.titleBimetallic Co–Ni based complex catalyst for hydrogen production by catalytic hydrolysis of sodium borohydride with an alternative approachen_US
dc.typeArticleen_US

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