Ternary SLE Measurements for the Systems H2O+ZnCl2+Zn(H2PO2)2 at T=(298, 313 and 333) K

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dc.authoridDemirci, Sevilay/0000-0003-4028-5699
dc.contributor.authorDemirci, Sevilay
dc.contributor.authorAdiguzel, Vedat
dc.contributor.authorSahin, Omer
dc.contributor.authorErge, Hasan
dc.date.accessioned2024-12-24T19:32:54Z
dc.date.available2024-12-24T19:32:54Z
dc.date.issued2022
dc.departmentSiirt Üniversitesi
dc.description.abstractThe solid-liquid equilibrium (SLE) of H2O+ZnCl2+Zn(H2PO2)(2) ternary system at 298, 313 and 333 K have been studied with the use of isothermal method. Solid phase compositions have been determined with Schreinemaker's method. H2O+ZnCl2+Zn(H2PO2)(2) ternary systems have simple eutectic type in 298, 333K. One invariant point, two invariant curves and two crystallization region have been observed in the phase diagrams at 298, 333K. Otherwise, One invariant point, three invariant curves and two crystallization region have been observed in the phase diagrams in 313K. In the crystallization regions; (i) Zn(H2PO2)center dot H2O and ZnCl2, (ii) Zn(H2PO2)(2), Zn(H2PO2)center dot H2O and ZnCl2, (iii) Zn(H2PO2)(2) and ZnCl2 salts have been observed at 298 K, 313K, and 333 K, respectively. In H2O+ZnCl2+Zn(H2PO2)(2) ternary system, the increasing salting-out effect of Zn(H2PO2)(2) on ZnCl2 with temperature.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [:114Z651]
dc.description.sponsorshipThis work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) with project no:114Z651.
dc.identifier.doi10.52568/000984/JCSP/44.01.2022
dc.identifier.endpage32
dc.identifier.issn0253-5106
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85124583936
dc.identifier.scopusqualityQ3
dc.identifier.startpage27
dc.identifier.urihttps://doi.org/10.52568/000984/JCSP/44.01.2022
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7871
dc.identifier.volume44
dc.identifier.wosWOS:000756086700004
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherChem Soc Pakistan
dc.relation.ispartofJournal of The Chemical Society of Pakistan
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPhase equilibria
dc.subjectTernary system
dc.subjectDensity
dc.subjectZinc chloride
dc.subjectZinc hypophosphite
dc.titleTernary SLE Measurements for the Systems H2O+ZnCl2+Zn(H2PO2)2 at T=(298, 313 and 333) K
dc.typeArticle

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