Metallo phthalocyanines bearing (2-((2-hydroxyethyl) (p-tolyl)amino)ethoxy) and (2-((2-phenoxyethyl) (p-tolyl)amino)ethoxy)phthalonitrile substituents: Synthesis, characterization, aggregation behavior, antioxidant and antibacterial activity

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dc.authoridOkumus, Veysi/0000-0002-5505-2700
dc.authoridCELEBI, METIN/0000-0003-1475-8878
dc.contributor.authorCelebi, Metin
dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorOkumus, Veysi
dc.contributor.authorOzdemir, Sadin
dc.date.accessioned2024-12-24T19:27:46Z
dc.date.available2024-12-24T19:27:46Z
dc.date.issued2014
dc.departmentSiirt Üniversitesi
dc.description.abstractThe novel phthalonitrile derivatives bearing (2-((2-hydroxyethyl)(p-tolyl)amino)ethoxy) and (2-((2-phenoxyethyl)(p-tolyl)amino)ethoxy)phthalonitrile substituents at peripheral position were prepared by a nucleophilic displacement reaction. Cyclotetramerization of these phthalonitrile derivatives in the presence of corresponding metal salts gave the new metallophthalocyanines. The novel compounds were characterized by using various spectroscopic data. The aggregation investigations carried out in different concentrations indicate that phthalocyanine compounds do not have any aggregation behavior for the concentration range of 10(-4)-10(-6) M in tetrahydrofuran. In vitro three antioxidant test methods, namely diphenylpicrylhydrazyl radical scavenging activity, metal chelating activity and reducing power were used to determine the antioxidant activity of compounds. Compounds were analyzed for their antibacterial activity against some bacteria by using the disk-diffusion method. (C) 2014 Elsevier B.V. All rights reserved.
dc.description.sponsorshipYuzuncu Yil University [2013-FBE-D059]
dc.description.sponsorshipThis study was supported by the Research Fund of Yuzuncu Yil University (2013-FBE-D059).
dc.identifier.doi10.1016/j.synthmet.2014.06.005
dc.identifier.endpage161
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-84903143986
dc.identifier.scopusqualityQ1
dc.identifier.startpage154
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2014.06.005
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6787
dc.identifier.volume195
dc.identifier.wosWOS:000341469300023
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectSynthesis
dc.subjectCharacterization
dc.subjectPhthalocyanines
dc.subjectAggregation
dc.subjectAntioxidant
dc.subjectAntibacterial activity
dc.titleMetallo phthalocyanines bearing (2-((2-hydroxyethyl) (p-tolyl)amino)ethoxy) and (2-((2-phenoxyethyl) (p-tolyl)amino)ethoxy)phthalonitrile substituents: Synthesis, characterization, aggregation behavior, antioxidant and antibacterial activity
dc.typeArticle

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