Removal and Preconcentration of Pb(II), Cr(III), Cr(VI) from the Aqueous Solution and Speciation of Cr(III)-Cr(VI) by Using Functionalized Amberlite XAD-16 Resin with Dithioethylenediamine

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dc.authoridTEGIN, IBRAHIM/0000-0002-5661-7195
dc.contributor.authorDolak, Ibrahim
dc.contributor.authorTegin, Ibrahim
dc.contributor.authorGuzel, Remziye
dc.contributor.authorZiyadanogullari, Recep
dc.date.accessioned2024-12-24T19:33:16Z
dc.date.available2024-12-24T19:33:16Z
dc.date.issued2010
dc.departmentSiirt Üniversitesi
dc.description.abstractAmberlit XAD-16 was functionalized using dithioethylenediamine as a ligand and characterized by elemental analysis and FTIR spectroscopy. The effects of contact time, pH, electrolyte and the concentration of eluent on separation and preconcentration of Pb(II), Cr(III) and Cr(VI) were studied. In addition, the batch capacity for each ion was determined under the optimum conditions. The preconcentration yields of Pb(II), Cr(III) and Cr(VI) were found to be 96.60 +/- 3.02, 102.20 +/- 3.00 and 100.64 +/- 2.24 %, respectively, with 500 times preconcentration factor under the optimum conditions. The speciation of Cr(III)-Cr(VI) was studied, it was determined that Cr(III) separated in 93.24 +/- 2.21 % yield from the solution containing Cr(III)-Cr(VI) by using Amberlit XAD-16-dithioethylenediamine and Cr(VI) remained in the solution at pH 4, while Cr(VI) separated in 101.43 +/- 3.09 % yield from the solution containing Cr(III)-Cr(VI) and Cr(III) remained in the solution. at pH 7.50 by using Amberlit XAD-16-dithioethylenediamine-Pb(II).
dc.description.sponsorshipDicle University [05-FF 20]
dc.description.sponsorshipThe authors would like to thank the Research fund of Dicle University for supporting this work under Project DUAPK 05-FF 20.
dc.identifier.endpage6124
dc.identifier.issn0970-7077
dc.identifier.issue8
dc.identifier.scopus2-s2.0-77955901386
dc.identifier.scopusqualityQ4
dc.identifier.startpage6117
dc.identifier.urihttps://hdl.handle.net/20.500.12604/8044
dc.identifier.volume22
dc.identifier.wosWOS:000279844900043
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAsian Journal Of Chemistry
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectRemoval
dc.subjectPreconcentration
dc.subjectSpeciation
dc.subjectAmberlite XAD-16
dc.subjectDithioethylenediamine
dc.titleRemoval and Preconcentration of Pb(II), Cr(III), Cr(VI) from the Aqueous Solution and Speciation of Cr(III)-Cr(VI) by Using Functionalized Amberlite XAD-16 Resin with Dithioethylenediamine
dc.typeArticle

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