Chiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions

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dc.authoridAydemir, Murat/0000-0002-4238-5012
dc.authoridBaysal, Akin/0000-0001-7294-6792
dc.authoridDURAP, Feyyaz/0000-0003-0899-1948
dc.contributor.authorBaysal, Akin
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorMeric, Nermin
dc.contributor.authorAk, Bunyamin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.date.accessioned2024-12-24T19:24:50Z
dc.date.available2024-12-24T19:24:50Z
dc.date.issued2017
dc.departmentSiirt Üniversitesi
dc.description.abstractMetal-catalyzed enantioselective transfer reduction of ketones to enantiomerically enriched chiral alcohols has recently attracted attention. Therefore, a series of methyl alkyl or alkyl/aryl ketones have been reduced by using Ru(II), Rh(I) and Ir(III) catalysts based on C (2)-symmetric chiral ferrocenyl phosphinite ligands. The corresponding optically active secondary alcohols were obtained in excellent conversions and moderate-to-good enantioselectivities. The best results were obtained with an iridium catalyst, giving up to 98% conversion and 80% ee.
dc.description.sponsorshipTUBITAK [111T419]; Dicle University [FEN.16.010, DUBAP FEN.15.021, FEN.15.022]
dc.description.sponsorshipPartial supports of this work by TUBITAK (Project Number: 111T419) and Dicle University (Project Numbers: FEN.16.010 (NMR), DUBAP FEN.15.021 and FEN.15.022) are gratefully acknowledged.
dc.identifier.doi10.1007/s11243-017-0140-1
dc.identifier.endpage372
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85016482059
dc.identifier.scopusqualityQ2
dc.identifier.startpage365
dc.identifier.urihttps://doi.org/10.1007/s11243-017-0140-1
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6132
dc.identifier.volume42
dc.identifier.wosWOS:000399456900011
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.titleChiral phosphinites as efficient ligands for enantioselective Ru(II), Rh(I) and Ir(III)-catalyzed transfer hydrogenation reactions
dc.typeArticle

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