Epoxy-activated acrylic particulate polymer-supported Co-Fe-Ru-B catalyst to produce H2 from hydrolysis of NH3BH3

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dc.authoridSAKA, Cafer/0000-0003-2534-5921
dc.contributor.authorIzgi, Mehmet Sait
dc.contributor.authorSahin, Omer
dc.contributor.authorOnat, Erhan
dc.contributor.authorSaka, Cafer
dc.date.accessioned2024-12-24T19:27:15Z
dc.date.available2024-12-24T19:27:15Z
dc.date.issued2020
dc.departmentSiirt Üniversitesi
dc.description.abstractEpoxy-activated acrylic particulate polymer, namely Eupergit CM, supported Co-Fe-Ru-B catalyst (EP/Co-Fe-Ru-B) for the first time was used to produce H-2 from hydrolysis of NH3BH3. The EP/Co-Fe-Ru-B showed very effective performance in the production of H-2 from the hydrolysis of NH3BH3. Various techniques such as XRD, SEM-EDS, ICP-OES, and TEM have been used to characterize these catalysts. The parameters on the hydrolysis reaction of NH3BH3 such as the effect of metal amount, the effect of Ru percentage, the effect of NH3BH3 concentration, the effect of NaOH concentration, the amount of catalyst, temperature, and catalyst durability were investigated in detail. Eupergit CM based poly-mer support and Ru particles have been found to be highly effective in H-2 production re-actions. The hydrogen production rate (HGR) of the EP/Co-Fe-Ru-B catalyst was found to be 36,978 mL/min/g(cat), which was quite good compared to the values reported in the literature. In addition, the activation energy (Ea) of the polymer-supported Co-Fe-Ru-B catalyst was determined as 24.91 kJ/mol. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.ijhydene.2020.06.048
dc.identifier.endpage22648
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue43
dc.identifier.scopus2-s2.0-85088590724
dc.identifier.scopusqualityQ1
dc.identifier.startpage22638
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2020.06.048
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6558
dc.identifier.volume45
dc.identifier.wosWOS:000564524600003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectEupergit CM
dc.subjectSupport material
dc.subjectCo-Fe-Ru-B
dc.subjectNH3BH3
dc.subjectHydrogen
dc.titleEpoxy-activated acrylic particulate polymer-supported Co-Fe-Ru-B catalyst to produce H2 from hydrolysis of NH3BH3
dc.typeArticle

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