Design of novel binuclear phthalocyanines formed by dioxyphenyl bridges: Synthesis and investigation of thermal and antioxidant properties

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dc.authoridhttps://orcid.org/0000-0002-5505-2700en_US
dc.contributor.authorAğırtaş, Salih
dc.contributor.authorGümüş, İlkay
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorDündar, Abdurrahman
dc.date.accessioned2019-12-25T11:55:09Z
dc.date.available2019-12-25T11:55:09Z
dc.date.issued2012en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstract4,4_-(1,4-Phenylenebis(oxy)diphthalonitrile was synthesized by reaction of hydroquinone with 4-nitrophthalonitrile. Binuclear metallophthalocyanines 2–4 were obtained by the reaction between 4,4_-(1,4-phenylenebis(oxy)diphthalonitrile and 4-(benzo [d] [1,3] dioxol- 5-ylmethoxy)phthalonitrile in the presence of metal salts. These new compounds were characterized by using elemental analysis, FTIR, 1H-NMR and UV/Vis spectroscopic data. Thermal properties of phthalocyanines 2-4 were investigated by TG and DTA. In addition, antioxidant properties of compounds II, 3 and 4 were investigated. Their radical-scavenging capacity and chelating effects was fully studied. The maximum 1,1-diphenyl-2-picrylhydrazyl radicals (DPPH) were obtained from compound 3. Chelating effects on ferrous ions were 91.6 % at concentration of 100 mgL–1 with compound II.en_US
dc.description.provenanceSubmitted by Veysi OKUMUŞ (veysiokumus@siirt.edu.tr) on 2019-12-23T18:42:46Z No. of bitstreams: 1 A8.pdf: 812832 bytes, checksum: 1fbe427887dc7dcdd8ccd7479108bc04 (MD5)en
dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-25T11:55:09Z (GMT) No. of bitstreams: 1 A8.pdf: 812832 bytes, checksum: 1fbe427887dc7dcdd8ccd7479108bc04 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-25T11:55:09Z (GMT). No. of bitstreams: 1 A8.pdf: 812832 bytes, checksum: 1fbe427887dc7dcdd8ccd7479108bc04 (MD5) Previous issue date: 2012en
dc.identifier.citationAğırtaş, M. S., Gümüş, İ., Okumus, V., & Dundar, A. (2012). Design of Novel Binuclear Phthalocyanines formed by Dioxyphenyl Bridges: Synthesis and Investigation of Thermal and Antioxidant Properties. Zeitschrift für anorganische und allgemeine Chemie, 638(11), 1868-1872.en_US
dc.identifier.endpage1872en_US
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84866723620
dc.identifier.scopusqualityQ3
dc.identifier.startpage1868en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2431
dc.identifier.volume638en_US
dc.indekslendigikaynakScopus
dc.institutionauthorOkumuş, Veysi
dc.language.isoenen_US
dc.publisherZeitschrift für anorganische und allgemeine Chemie.en_US
dc.relation.ispartofZeitschrift für anorganische und allgemeine Chemie.
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKG_20241224
dc.subjectPhthalocyaninesen_US
dc.subjectAntioxidantsen_US
dc.subjectThermal propertiesen_US
dc.subjectSynthesisen_US
dc.subjectBinuclear complexesen_US
dc.titleDesign of novel binuclear phthalocyanines formed by dioxyphenyl bridges: Synthesis and investigation of thermal and antioxidant propertiesen_US
dc.typeArticleen_US

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