Application of Half-Sandwich Metal-Phosphinite Compounds to Biological Activities: Determine the energies of the HOMO and LUMO levels

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dc.authoridISLAM, Sholpan/0000-0003-1672-5877
dc.authoridDUNDAR, ABDURRAHMAN/0000-0002-7930-1054
dc.contributor.authorMeric, Nermin
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorZazybin, Alexey
dc.contributor.authorGuzel, Remziye
dc.contributor.authorKayan, Cezmi
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorDundar, Abdurrahman
dc.date.accessioned2024-12-24T19:24:23Z
dc.date.available2024-12-24T19:24:23Z
dc.date.issued2023
dc.departmentSiirt Üniversitesi
dc.description.abstractMononuclear transition metal complexes 1-(furan-2-yl)ethyldiphenyl[dichloro(eta(6)-p-cymene)ruthenium(II)]phosphinite, (2), 1-(furan-2-yl)ethyldiphenyl[dichloro(eta(6)-benzene) ruthenium(II)] phosphinite (3), 1-(furan-2-yl)ethyldipheny[chloro(eta(4)-1,5-cyclooctadiene)rhodium(I)]phosphinite (4), 1-(furan-2-yl)ethyldiphenyl[dichloro (eta(5)pentamethylcyclopentadienyl)iridium (III)] phosphinite (5) were synthesized and characterized by microanalysis, infrared, MS, and NMR spectroscopy. The biological activities of the complexes were also tested. Compounds 2 and 5 were the best complexes at DPPH radical scavenging and reducing power activity at 73.27 % and 0.41 at 200 mu g/mL, respectively. The highest antimicrobial activity exhibited by complex 3 as 14 mm inhibition zone against S. aureus. All of the complexes have cleaved the DNA from the double-strand and exhibited three bands on gel electrophoresis. Moreover, cyclic voltammetry studies of the phosphinite complexes were carried out to determine the energies of the HOMO and LUMO levels as well as to estimate their electrochemical and some electronic properties.
dc.description.sponsorshipScience Committee of the Ministry of Education and Science of the Republic of Kazakhstan; Dicle University; [IRNAP08857516]; [FEN.20.005]
dc.description.sponsorshipAcknowledgements The research is funded by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No: IRNAP08857516). Partial support of this work by Dicle University (Project number: FEN.20.005) is gratefully acknowledged.
dc.identifier.doi10.1002/zaac.202200126
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue2
dc.identifier.scopus2-s2.0-85142272576
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1002/zaac.202200126
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5956
dc.identifier.volume649
dc.identifier.wosWOS:000888397300001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPhosphinite Ligand
dc.subjectTransition metal
dc.subjectBiological Study
dc.subjectElectron transport
dc.titleApplication of Half-Sandwich Metal-Phosphinite Compounds to Biological Activities: Determine the energies of the HOMO and LUMO levels
dc.typeArticle

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