Microwave treatment and fluorine addition on Co-B catalyst to improve the hydrogen production rate

[ X ]

Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor & Francis Inc

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this paper, microwave heating treatment process and fluorine addition over Co-B-F catalyst was applied to produce hydrogen via the hydrolysis of NaBH4. The effects of microwave heating treatment time, microwave heating treatment power, microwave inert gases and temperature on the catalyst were studied. X-ray absorption spectrometer, scanning electron microscopy coupled to energy-dispersive spectroscopy, nitrogen adsorption analyzer and infrared spectrometer were performed for the chemical characterization of the catalysts. It was found that Co-B-F and microwave-treated Co-B-F catalysts exhibited excellent catalytic activity to produce hydrogen. The rates of the maximum hydrogen production for untreated and microwave-treated Co-B-F catalysts are 1868 and 3400 mL/g/min, respectively.

Açıklama

Anahtar Kelimeler

Catalyst, cobalt-boron, fluorine, generation, heating, hydrogen, microwave, rate, sodium borohydride, treatment

Kaynak

Materials and Manufacturing Processes

WoS Q Değeri

Q2

Scopus Q Değeri

Q1

Cilt

33

Sayı

2

Künye