Synthesis and spectroscopic characterization of a new macrocyclic Schiff base formed by the reaction of 1,5-bis(2-formylphenyl)pentane and 2,6-diaminopyridine, and a study of its metal complexes

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dc.authoridIlhan, Salih/0000-0003-0779-2744
dc.authoridtemel, hamdi/0000-0001-9225-7425
dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-12-24T19:28:02Z
dc.date.available2024-12-24T19:28:02Z
dc.date.issued2009
dc.departmentSiirt Üniversitesi
dc.description.abstractA new dialdehyde 1,5-bis(2-formylphenyl)pentane was synthesized from 1,5-dibromopentane with salicylaldehyde and K2CO3; macrocyclic ligand was synthesized by reaction of 2,6-diaminopyridine and 1,5-bis(2-formylphenyl) pentane. Cu(II), Ni(II), Pb(II), Zn(II), Cd(II) and La(III) complexes were synthesized by reaction of the ligand and Cu(ClO4)(2) center dot 6H(2)O, Ni(ClO4)(2) center dot 6H(2)O, Pb(ClO4)(2) center dot 6H(2)O, Zn(ClO4)(2) center dot 6H(2)O, Cd(ClO4)(2) center dot 6H(2)O and La(ClO4)(3) center dot 6H(2)O, respectively. The ligand and its metal complexes have been characterized by elemental analysis, IR, H-1 and C-13 NMR, UV-Vis spectra, magnetic susceptibility, conductivity measurements and mass spectra. All complexes are diamagnetic and Cu(II) complex is binuclear.
dc.identifier.doi10.1080/00958970802251765
dc.identifier.endpage464
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue3
dc.identifier.scopus2-s2.0-58149117568
dc.identifier.scopusqualityQ3
dc.identifier.startpage456
dc.identifier.urihttps://doi.org/10.1080/00958970802251765
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6897
dc.identifier.volume62
dc.identifier.wosWOS:000261921800012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subject1,5-Bis(2-formylphenyl)pentane
dc.subject2,6-Diaminopyridine
dc.subjectMacrocyclic Schiff base
dc.subjectMacrocyclic Schiff-base complexes
dc.titleSynthesis and spectroscopic characterization of a new macrocyclic Schiff base formed by the reaction of 1,5-bis(2-formylphenyl)pentane and 2,6-diaminopyridine, and a study of its metal complexes
dc.typeArticle

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