Radiation damage produced in powder of ?-(methylamino)isobutyric acid, ?-aminoisobutyric acid methyl ester hydrochloride and diethylmalonic acid
[ X ]
Tarih
2009
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The electron paramagnetic resonance spectra of gamma-irradiated powders of alpha-(methylamino) isobutyric acid - CH(3)NHC(CH(3))(2)COOH, alpha-aminoisobutyric acid methyl ester hydrochloride - NH(2)(CH(3))(2)CCOOCH(3) HCl, and diethylmalonic acid - (CH(3)CH(2))(2)C(COOH)(2) have been investigated at room temperature. It has been found that gamma-irradiation produces the (CH(3))(2)(C) over dotCOOH radical in the first, the (CH(3))(2)(C) over dotCOOCH(3) radical in the second and the (CH(3)CH(2))(2)(C) over dot COOH radical in the third compound. The spectra were computer-simulated. The g values and the hyperfine coupling constants of the unpaired electron with the environmental methyl, methylene protons and OH proton were determined. The results were found to be in good agreement with the existing literature data and theoretical predictions.
Açıklama
Anahtar Kelimeler
EPR, amino-acid derivatives, gamma-irradiation, free radicals, malonic acid derivatives
Kaynak
Radiation Effects and Defects in Solids
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
164
Sayı
11
