Synthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives

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dc.authoridBaysal, Akin/0000-0001-7294-6792
dc.authoridDurgun, Mustafa/0000-0003-3012-7582
dc.authoridAydemir, Murat/0000-0002-4238-5012
dc.authoridKILIC, Ahmet/0000-0001-9073-4339
dc.authoridDURAP, Feyyaz/0000-0003-0899-1948
dc.contributor.authorKilic, Ahmet
dc.contributor.authorKayan, Cezmi
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorDurgun, Mustaf
dc.contributor.authorBaysal, Akin
dc.contributor.authorTas, Esref
dc.date.accessioned2024-12-24T19:24:07Z
dc.date.available2024-12-24T19:24:07Z
dc.date.issued2011
dc.departmentSiirt Üniversitesi
dc.description.abstractTwo new boron complexes were synthesized from N-[3-(methylmercapto)aniline]-3,5-di-tert-butylsalicylaldimine (LH) with boron reagent BPh3 or BF3 center dot Et2O. These boron complexes are stable and easily soluble in protic solvents such as ethanol (C2H5OH) but hardly soluble in nonprotic solvents such as chloroform (CHCl3), dichloromethane (CH2Cl2) and tetrahydrofuran (THF). All new boron complexes have been fully characterized by both analytical and spectroscopic methods. The catalytic activities of complexes [LBPh2], 2, and [LBF2], 3, in the transfer hydrogenation of acetophenone derivatives were tested. Stable boron complexes were found to be efficient catalysts in the transfer hydrogenation of aromatic ketones in good conversions up to 99% in the presence of iso-PrOH/KOH. Copyright (C) 2011 John Wiley & Sons, Ltd.
dc.description.sponsorshipHarran University; Dicle University [DUAPK 05-FF-27]
dc.description.sponsorshipPartial support of this work by Harran University and Dicle University (project number DUAPK 05-FF-27) is gratefully acknowledged.
dc.identifier.doi10.1002/aoc.1779
dc.identifier.endpage394
dc.identifier.issn0268-2605
dc.identifier.issue5
dc.identifier.scopus2-s2.0-79955041839
dc.identifier.scopusqualityQ1
dc.identifier.startpage390
dc.identifier.urihttps://doi.org/10.1002/aoc.1779
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5838
dc.identifier.volume25
dc.identifier.wosWOS:000289515300010
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectboron complexes
dc.subjecttransfer hydrogenation
dc.subjectBPh3
dc.subjectBF3 center dot Et2O
dc.subjectsynthesis
dc.titleSynthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives
dc.typeArticle

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