Synthesis, Spectral Characterization and Electrochemical Investigations of Mononuclear Cu (II), Ni (II) and Co (II) Metal Complexes Containing Different New vic-dioxime Groups

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dc.authoridyilmaz, ismail/0000-0002-5046-7456
dc.authoridDurgun, Mustafa/0000-0003-3012-7582
dc.authoridKILIC, Ahmet/0000-0001-9073-4339
dc.contributor.authorTas, Esref
dc.contributor.authorKara, Hatice
dc.contributor.authorDurgun, Mustafa
dc.contributor.authorKilic, Ahmet
dc.contributor.authorYilmaz, Ismail
dc.date.accessioned2024-12-24T19:28:20Z
dc.date.available2024-12-24T19:28:20Z
dc.date.issued2009
dc.departmentSiirt Üniversitesi
dc.description.abstractThree new vic-dioxime: N-(2-methyl-2-butylamine)-anti-p-tolylglyoxime (L1H2), N-(4-amino-2,2,6,6-tetramethylpiperidine)-anti-p-tolylglyoxime (L2H2) and N,N'-(4-amino-2,2,6,6-tetramethylpiperidine)-anti-glyoxime (L3H2) were prepared by the reaction of anti-p-tolylchloroglyoxime and anti-dichloroglyoxime with 2-methyl-2-butylamine and 4-amino-2,2,6,6-tetramethylpiperidine in absolute THF at -15 degrees C. Mononuclear metal complexes with a metal-ligand ratio of 1:2 were prepared using Cu(II), Ni(II) and Co(II) salts. FT-IR spectra show that the ligands act in a tetradentate manner and coordinates N4 donor groups of ligands to Cu(II), Ni(II) and Co(II) ions. The Cu(II) complexes of these ligands are proposed to be square-planar; the Ni(II) and Co(II) complexes are proposed to be octahedral with two water molecules as axial ligands. The ligands and their metal complexes were characterized by elemental analyses, Ft-IR, UV-Vis, 1H and 13C-NMR spectra, magnetic susceptibility measurements and cyclic voltammetry. The electrochemical behavior of the Ni(II), Co(II) and Cu(II) complexes was investigated by cyclic voltammetry in DMSO as well.
dc.description.sponsorshipScientific Research Council of Harran University [HUBAK-744]
dc.description.sponsorshipThis work was supported by the Scientific Research Council of Harran University (Project No: HUBAK-744).
dc.identifier.doi10.1080/15533170903129612
dc.identifier.endpage387
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue7
dc.identifier.scopus2-s2.0-69549115116
dc.identifier.scopusqualityN/A
dc.identifier.startpage379
dc.identifier.urihttps://doi.org/10.1080/15533170903129612
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7024
dc.identifier.volume39
dc.identifier.wosWOS:000268875400004
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectelectrochemical investigations
dc.subjectH-bonding
dc.subjectmetal complexes
dc.subjectoximes
dc.titleSynthesis, Spectral Characterization and Electrochemical Investigations of Mononuclear Cu (II), Ni (II) and Co (II) Metal Complexes Containing Different New vic-dioxime Groups
dc.typeArticle

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