Half-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties

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dc.authoridKAYAN, Cezmi/0000-0001-5700-8546
dc.authoridISIK, UGUR/0000-0003-1010-9563
dc.contributor.authorIsik, Ugur
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorMeric, Nermin
dc.contributor.authorGuzel, Remziye
dc.contributor.authorKerimkulova, Aygul
dc.contributor.authorAkimbek, Arailym
dc.contributor.authorOkumus, Veysi
dc.date.accessioned2024-12-24T19:24:22Z
dc.date.available2024-12-24T19:24:22Z
dc.date.issued2024
dc.departmentSiirt Üniversitesi
dc.description.abstractRuthenium(II) and iridium(III) complexes of phosphinites including imidazole moiety were synthesized and characterized by microanalysis, IR, MS, and NMR spectroscopies. Antibacterial activity against Gram-positive and Gram-negative bacterial strains was assessed in all complexes. The highest radical scavenging (72.2 %) was obtained for [3-(3-chloro-2-({[dichloro(eta 6-benzene)ruthenium]diphenylphosphanyl}oxy)propyl)-1-butyl-1H-imidazol-3-ium chloride], 4 at 200 mu g/mL concentration, while [3-(3-chloro-2-({[dichloro(eta 5-pentamethylcyclopentadienyl)-iridium]diphenylphosphanyl}oxy)pro-pyl)-1-butyl-1H-imidazol-3-ium chloride], 6 demonstrated the highest antibacterial activity as 13 mm inhibition zone against E. hirea. Furthermore, optical and electrochemical featured of metal complexes containing imidazole phosphinite were investigated utilizing UV-vis absorption and cyclic voltammetry techniques. Consequently, all complexes can be proposed as metal-based charge convertible phosphinite complexes which may be employed as new generation and synergistic Dye-Sensitized Solar Cell (DSSC) materials. Ruthenium(II) and iridium(III) complexes of phosphinites including imidazole moiety are synthesized and characterized by microanalysis, IR, MS, and NMR spectroscopies. Their antibacterial activity against Gram-positive and Gram-negative bacterial strains is assessed. Furthermore, optical and electrochemical features of the metal complexes are investigated utilizing UV-vis absorption and cyclic voltammetry techniques. image
dc.description.sponsorshipScience Committee of the Ministry of Education and Science of the Republic of Kazakhstan; Dicle University [FEN.23.019]; [AP19676664]
dc.description.sponsorshipThe research is funded by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No: AP19676664). Partial supports of this work by Dicle University (Project number: FEN.23.019) is gratefully acknowledged.
dc.identifier.doi10.1002/slct.202304785
dc.identifier.issn2365-6549
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85184711433
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1002/slct.202304785
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5939
dc.identifier.volume9
dc.identifier.wosWOS:001159739100001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistryselect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectIonic Liquid
dc.subjectImidazolium Salt
dc.subjectPhosphinite Ligand
dc.subjectTransition Metal
dc.subjectElectrochemical Properties
dc.subjectAntibacterial/Biological Study
dc.titleHalf-sandwich ruthenium(II) and iridium(III) complexes of imidazole based phosphinite ligands: antioxidant and antibacterial activities as well as electrochemical properties
dc.typeArticle

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