The chemometric study of multi-elemental composition in cultivated rhubarb from Iraq Kurdish Region and Turkiye Siirt

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dc.authoridMahmood Fattah, Bakhtiyar/0009-0005-1039-7077
dc.authoridTEGIN, IBRAHIM/0000-0002-5661-7195
dc.contributor.authorTegin, Ibrahim
dc.contributor.authorFattah, Bakhtiyar Mahmood
dc.contributor.authorCanpolat, Gurbet
dc.contributor.authorAcar, Orhan
dc.date.accessioned2024-12-24T19:28:10Z
dc.date.available2024-12-24T19:28:10Z
dc.date.issued2023
dc.departmentSiirt Üniversitesi
dc.description.abstractThe concentrations of 30 elements (Li, Be, B, Na, Mg, P, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Cd, Sn, Sb, Ba, La, Ce, Pt, Tl and Pb) in cultivated stems of rhubarb samples collected from the Kurdish region of Iraq (Sor, Rash, Karajar, Gara and Qalandar) and the Siirt region of Turkey (Pervari and Sirvan) were determined by Inductively Coupled Plasma - Mass (ICP-MS) spectrometry after acid digestion by a microwave digestor (Berghof Speedwawe MWS-3). The analysis revealed that the levels of Mg, K and P in the samples found were higher than other metals. Conversely, the presence of metals such as Pt, Tl, Be and Ar was found to be at significantly lower concentrations. The levels of the elements determined in the cultivated rhubarb samples were subjected to chemometric analysis using correlation analysis, principal component analysis (PCA) and cluster analysis (CA) techniques for the classification of metal content and the places of samples. Linear correlation coefficient values representing the element-to-element correlation data were analysed at the 95% and 99% confidence levels. The results of the study showed that the rhubarb samples could be classified into three groups based on their elemental compositions, using the PCA method. These findings were found to be consistent with the results obtained through cluster analysis (CA). This suggests that the chemometric techniques used in this study are effective for identifying patterns and relationships in complex datasets and could be useful for analysing other samples and identifying their origins. Overall, this study provides important insights into the elemental composition of Rhubarb samples and could have implications for food safety and quality control.
dc.description.sponsorshipSiirt University Scientific Research Unit [2017-SIUEFEB-80]
dc.description.sponsorshipThis manuscript has been prepared from MSc. thesis (Master's thesis, Republic of Turkey, Siirt University, Institute of Science). Siirt University Scientific Research Unit supported this study (2017-SIUEFEB-80). The authors have acknowledged to master of science (MSc.) thesis prepared by I. Tegin-advisor, B. M. F. Fattah-Student, Gurbet Canpolat-Contributor and Orhan Acar-Writing and Preparing the Manuscript.
dc.identifier.doi10.1080/03067319.2023.2209019
dc.identifier.issn0306-7319
dc.identifier.issn1029-0397
dc.identifier.scopus2-s2.0-85159276470
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1080/03067319.2023.2209019
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6928
dc.identifier.wosWOS:000987912700001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofInternational Journal of Environmental Analytical Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectChemometric analysis
dc.subjectcultivated rhubarb sample
dc.subjectcluster analysis
dc.subjectelements
dc.subjectprincipal component analysis
dc.titleThe chemometric study of multi-elemental composition in cultivated rhubarb from Iraq Kurdish Region and Turkiye Siirt
dc.typeArticle

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