Development of highly efficient and reusable Ruthenium complex catalyst for hydrogen evolution

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dc.contributor.authorKilinc, Dilek
dc.contributor.authorSahin, Omer
dc.date.accessioned2024-12-24T19:27:16Z
dc.date.available2024-12-24T19:27:16Z
dc.date.issued2022
dc.departmentSiirt Üniversitesi
dc.description.abstractHerein, we report an efficient, environmentally friendly and stable catalyst development to hydrogen evolution from sodium borohydride hydrolysis. For this purpose, Ruthenium complex catalyst successfully fabricated via 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine ligand and RuCl3.H2O salt. Ru complex catalyst was identified with X-Ray Diffraction Analysis, Infrared Spectroscopy, Elemental Analysis, Transmission electron microscopy, Scanning Electron Microscope and Brunauer-Emmett-Teller Surface Area Analysis. According to the analysis results, it was confirmed that Ru complex catalyst was successfully synthesized. Ru complex was used as a catalyst in NaBH4 hydrolysis. The kinetic performance of Ru complex catalyst was evaluated at various reaction tempera-tures, various sodium borohydride concentration, catalyst concentration and sodium hy-droxide concentration in hydrogen evolution. The apparent activation energy for the hydrolysis of sodium borohydride was determined as 25.8 kJ mol(-1). With fully conversion, the promised well durability of Ru complex was achieved by the five consecutive cycles for hydrogen evolution in sodium borohydride hydrolysis The hydrogen evolution rates were 299,220 and 160,832 mL H-2 g(cat)(-1) min(-1) in order of at 50 degrees C and 30 degrees C. Furthermore, the proposed mechanism of Ru complex catalyzed sodium borohydride hydrolysis was defined step by step. This study provides different insight into the rational design and utilization and catalytic effects of ruthenium complex in hydrogen evolution performance. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.ijhydene.2021.11.051
dc.identifier.endpage3885
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85120060457
dc.identifier.scopusqualityQ1
dc.identifier.startpage3876
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2021.11.051
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6570
dc.identifier.volume47
dc.identifier.wosWOS:000744010700014
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectHydrolysis
dc.subjectRu complex
dc.subjectHydrogen
dc.subjectSodium borohydride
dc.titleDevelopment of highly efficient and reusable Ruthenium complex catalyst for hydrogen evolution
dc.typeArticle

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