Synthesis and spectral studies of macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes derived from 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives

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dc.authoridPasa, Salih/0000-0002-4792-8821
dc.authoridIlhan, Salih/0000-0003-0779-2744
dc.authoridtemel, hamdi/0000-0001-9225-7425
dc.contributor.authorIlan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorPasa, Salih
dc.date.accessioned2024-12-24T19:25:24Z
dc.date.available2024-12-24T19:25:24Z
dc.date.issued2009
dc.departmentSiirt Üniversitesi
dc.description.abstractEight new macrocyclic complexes were synthesized by template reaction of 1,4-bis(3-aminopropoxy)butane with metal nitrate and 1,3-bis(2-formylphenyl)propane or 1,4-bis(2-formylphenyl)butane and their structures were proposed on the basis of elemental analysis, FTIR, UV-vis, molar conductivity measurements, H-1 NMR and mass spectra. The metals to ligand molar ratios of the complexes were found to be 1:1. The complexes are 1:2 electrolytes for Pb(II), Zn(II) and Cd(II) complexes and 1:3 electrolytes for La(III) as shown by their molar conductivities (Lambda(m)) in DMSO at 10(-3) mol L-1. Due to the existence of free ions in these complexes, such complexes are electrically conductive. The configurations of La(III) and Pb(II) were proposed to probably octahedral and Zn(II) and Cd(II) complexes were proposed to probably tetrahedral. (C) 2008 Salih Ilhan. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
dc.identifier.doi10.1016/j.cclet.2008.12.008
dc.identifier.endpage343
dc.identifier.issn1001-8417
dc.identifier.issn1878-5964
dc.identifier.issue3
dc.identifier.scopus2-s2.0-59349112340
dc.identifier.scopusqualityQ1
dc.identifier.startpage339
dc.identifier.urihttps://doi.org/10.1016/j.cclet.2008.12.008
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6396
dc.identifier.volume20
dc.identifier.wosWOS:000264377000024
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofChinese Chemical Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectMacrocyclic Schiff base
dc.subjectMacrocyclic complexes
dc.subjectSalicylaldehyde derivatives
dc.subject1,4-Bis(3-aminopropoxy)butane
dc.titleSynthesis and spectral studies of macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes derived from 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives
dc.typeArticle

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