Synthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions

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dc.authoridBaysal, Akin/0000-0001-7294-6792
dc.authoridAydemir, Murat/0000-0002-4238-5012
dc.authoridDURAP, Feyyaz/0000-0003-0899-1948
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akin
dc.date.accessioned2024-12-24T19:24:07Z
dc.date.available2024-12-24T19:24:07Z
dc.date.issued2016
dc.departmentSiirt Üniversitesi
dc.description.abstractA series of new chiral C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes have been synthesized and for the first time used as catalysts in the palladium-catalysed asymmetric intermolecular Heck coupling reactions of 2,3-dihydrofuran with iodobenzene or aryl triflate. Under optimized conditions, products were obtained with high conversions and moderate to good enantioselectivities. The new C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes were characterized using multinuclear NMR and Fourier transform infrared spectroscopies and elemental analysis. Copyright (c) 2015 John Wiley & Sons, Ltd.
dc.description.sponsorshipDicle University Science and Technology Application and Research Center (DUBTAM); Dicle University Research Fund DUBAP [13-FF-114]
dc.description.sponsorshipAnalysis and research were supported by the Dicle University Science and Technology Application and Research Center (DUBTAM) which is gratefully acknowledged. Financial support from Dicle University Research Fund DUBAP (project no. 13-FF-114) is gratefully acknowledged. The authors thank Prof. Dr Yilmaz Turgut (Dicle University) for valuable contributions.
dc.identifier.doi10.1002/aoc.3416
dc.identifier.endpage198
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue4
dc.identifier.scopus2-s2.0-84953432819
dc.identifier.scopusqualityQ1
dc.identifier.startpage193
dc.identifier.urihttps://doi.org/10.1002/aoc.3416
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5839
dc.identifier.volume30
dc.identifier.wosWOS:000372924700004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectpalladium(II)
dc.subjectC-2 symmetry
dc.subjectphosphinite
dc.subjectasymmetric Heck coupling
dc.titleSynthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions
dc.typeArticle

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