Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes

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dc.authoridDURAP, Feyyaz/0000-0003-0899-1948
dc.authoridAydemir, Murat/0000-0002-4238-5012
dc.authoridBaysal, Akin/0000-0001-7294-6792
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorAk, Bunyamin
dc.contributor.authorBaysal, Akin
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-12-24T19:27:27Z
dc.date.available2024-12-24T19:27:27Z
dc.date.issued2016
dc.departmentSiirt Üniversitesi
dc.description.abstractKnown Ru(II), Rh(I) and Ir(III) complexes of C-2-symmetric ferrocenyl based chiral bis(phoshinite) ligands were catalyzed the asymmetric transfer hydrogenation of alkyl/aryl or alkyl methyl ketones. Corresponding secondary alcohols were obtained with high enantioselectivities up to 98% ee and reactivities using iso-propanol as the hydrogen source. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipTUBITAK [111T419]
dc.description.sponsorshipFinancial support from TUBITAK (Grant number: 111T419) is gratefully acknowledged.
dc.identifier.doi10.1016/j.jorganchem.2016.05.025
dc.identifier.endpage97
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84974603635
dc.identifier.scopusqualityQ2
dc.identifier.startpage92
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2016.05.025
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6635
dc.identifier.volume818
dc.identifier.wosWOS:000380751600013
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectTransfer hydrogenation
dc.subjectC-2-symmetry
dc.subjectFerrocenyl ligands
dc.subjectPhosphinite
dc.titleAsymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes
dc.typeArticle

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