Metallo and metal free phthalocyanines bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents: Synthesis, characterization, aggregation behavior, electronic, antioxidant and antibacterial properties

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dc.authoridDUNDAR, ABDURRAHMAN/0000-0002-7930-1054
dc.authoridGumus, Selcuk/0000-0002-8628-8943
dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorGuven, M. Emin
dc.contributor.authorGumus, Selcuk
dc.contributor.authorOzdemir, Sadin
dc.contributor.authorDundar, Abdurrahman
dc.date.accessioned2024-12-24T19:27:46Z
dc.date.available2024-12-24T19:27:46Z
dc.date.issued2014
dc.departmentSiirt Üniversitesi
dc.description.abstractAs starting material the phthalonitrile derivative bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents at peripheral position was prepared by a nucleophilic displacement reaction. Cyclotetramerization of 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalonitrile derivative in the presence of corresponding metal salts gave the new metallophthalocyanines. Metal free phthalocyanine was obtained from the reaction of 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalonitrile units. The novel compounds have been characterized by using various spectroscopic data. The aggregation investigations carried out in different concentrations indicate that 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalocyanine compounds do not have any aggregation behavior for the concentration range of 10(-4)-10(-5) M in tetrahydrofuran. The antioxidant activities of novel compounds were analyzed through radical scavenging ability of 1,1-dipheny1-2-picrylhydrazyl, chelating ability to ferrous ions and reducing power. In addition to these, the antibacterial activities of compounds were investigated. Moreover, the ground-state geometries of the complexes were optimized using B3LYP/6-31G(d,p) level of density functional theory in order to predict the three-dimensional geometries and electronic structure. (C) 2014 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2014.06.004
dc.identifier.endpage184
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-84903316908
dc.identifier.scopusqualityQ1
dc.identifier.startpage177
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2014.06.004
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6786
dc.identifier.volume195
dc.identifier.wosWOS:000341469300026
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectSynthesis
dc.subjectPhthalocyanines
dc.subjectAggregation
dc.subjectAntioxidant
dc.subjectAntibacterial
dc.subjectElectronic structure
dc.titleMetallo and metal free phthalocyanines bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents: Synthesis, characterization, aggregation behavior, electronic, antioxidant and antibacterial properties
dc.typeArticle

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