Synthesis of thiol-glycol-functionalized carbon nanotubes and characterization with FTIR, TEM, TGA, and NMR technics

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dc.authoridCICEK, Baki/0000-0003-1257-1188
dc.authoridCALISIR, Umit/0000-0001-7699-2008
dc.contributor.authorCalisir, Umit
dc.contributor.authorCicek, Baki
dc.date.accessioned2024-12-24T19:24:53Z
dc.date.available2024-12-24T19:24:53Z
dc.date.issued2020
dc.departmentSiirt Üniversitesi
dc.description.abstractCarbon nanotube is one of the important topics of interest in the nanotechnology science. Many scientists have been interested in surface-modified nanotubes for decades. In this study, multi-walled carbon nanotubes (MWCNTs) were functionalized with polyethylene glycol and dithiols in esterification reactions. The MWNTs were first carboxylate-functionalized. The carboxylated MWCNTs were acyl chlorite substituted. The functionalized MWNTs were used as the precursor to esterification of polyethylene glycols and thiols. The reactions were performed catalysts or non-catalysts, solvent-free and solvent media, using microwave-assisted and classical methods. The synthesized compounds were characterized by FTIR, TGA, TEM and NMR techniques. We investigate the advantage of microwave synthesis method in terms of time and solvent in Green Chemistry. The obtained compounds exhibit very interesting results in their complexes with metals due to containing free hydroxyl and thiol groups.
dc.description.sponsorshipBalikesir University Scientific Research Projects Unit [BAP:2017/080, BAP:2019/066]
dc.description.sponsorshipIn this study, both Baki Cicek and Umit Calisir designed the study, performed all experiments/analysis, and evaluated the results and prepared the manuscript. Baki Cicek was the supervisor of Umit Calisir during this work, which is presented as a Ph.D. thesis. This work has been supported by Balikesir University Scientific Research Projects Unit with Project Number BAP:2017/080 and BAP:2019/066.
dc.identifier.doi10.1007/s11696-020-01158-6
dc.identifier.endpage3302
dc.identifier.issn2585-7290
dc.identifier.issn1336-9075
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85083677471
dc.identifier.scopusqualityQ2
dc.identifier.startpage3293
dc.identifier.urihttps://doi.org/10.1007/s11696-020-01158-6
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6176
dc.identifier.volume74
dc.identifier.wosWOS:000527905800001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer International Publishing Ag
dc.relation.ispartofChemical Papers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectMWCNT
dc.subjectSubstituted MWCNT
dc.subjectMicrowave-assisted synthesis
dc.subjectEsterification
dc.subjectSurface modification
dc.titleSynthesis of thiol-glycol-functionalized carbon nanotubes and characterization with FTIR, TEM, TGA, and NMR technics
dc.typeArticle

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