Semi-methanolysis reaction of potassium borohydride with phosphoric acid for effective hydrogen production

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dc.contributor.authorBalbay, Asım
dc.contributor.authorSaka, Cafer
dc.date.accessioned2019-11-05T12:59:36Z
dc.date.available2019-11-05T12:59:36Z
dc.date.issued2018-11-15
dc.departmentBelirleneceken_US
dc.description.abstractThe methanol and water solvents were used for the production of hydrogen from potassium borohydride. In addition, phosphoric acid was selected as the green catalyst so that this semi-methanolysis reaction would be more effective for the first time. The semimethanolysis of potassium borohydride is investigated depend on potassium borohydride, phosphoric acid concentrations and temperatures. The maximum normalized hydrogen production rate obtained from this semi-methanolysis reaction with 1 M phosphoric acid as a catalyst was 5779 ml min 1 g 1. In addition, this semi-methanolysis reaction was completed in 5 s. Kinetic studies have been carried out with the power law kinetic model. The activation energy obtained for this semi-methanolysis reaction is 1.45 kJ mol 1.en_US
dc.identifier.issn0360-3199
dc.identifier.scopus2-s2.0-85055089312
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://hdl.handle.net/20.500.12604/871
dc.identifier.wosWOS:000450377300011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier-Hydrogen Energyen_US
dc.relation.publicationcategoryUluslararası Hakemli Dergi Makalesien_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKG_20241224
dc.subjectSemi-methanolysis phosphoric acid Potassium borohydride Hydrogenen_US
dc.titleSemi-methanolysis reaction of potassium borohydride with phosphoric acid for effective hydrogen productionen_US
dc.typeArticleen_US

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