Effective TiO2 supported Cu-Complex catalyst in NaBH4 hydrolysis reaction to hydrogen generation
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Tarih
2019
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This paper reports the experimental results on using TiO2 based Cu(II)-Schiff Base complex catalyst for hydrolysis of NaBH4. In the presence of Cu-Schiff Base complex which we reported in advance [1] and with titanium dioxide supports a novel catalyst named TiO2 supported 4-4'-Methylenbis (2,6-diethyl)aniline-3,5-di-tert-buthylsalisylaldimine-Cu complex is prepared, successfully. The synthesized catalyst was characterized by means of X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Brunauer-Emmett-Teller Surface Area Analysis (BET) and Fourier Transform Infrared Spectroscopy (FT-IR). The as prepared catalyst was employed to generate hydrogen through hydrolysis reaction of NaBH4. Effects of different parameters (e.g. amount of Cu-Schiff Base complex in all catalyst, percentage of NaBH4, percentage of NaOH, amount of TiO2 supported Cu-Schiff Base complex catalyst and different temperatures) are also investigated. A high apparent activation energy (Ea), 25,196 kJ.mol(-)1 is calculated for hydrolysis of NaBH4 at 20-50 degrees C. Hydrogen generation rate was 14,020 mL H-2/g(cat).min and 22,071 mL H-2/g(cat).min in order of 30 degrees C and 50 degrees C. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Açıklama
3rd International Hydrogen Technologies Congress (IHTEC) -- MAR 15-18, 2018 -- Alanya Alaaddin Keykubat Univ, TURKEY
Anahtar Kelimeler
Cu-complex, Catalyst, Schiff base, Hydrolysis, NaBH4
Kaynak
International Journal of Hydrogen Energy
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
44
Sayı
34
