Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction
| dc.contributor.author | Kilinc, Dilek | |
| dc.contributor.author | Sahin, Omer | |
| dc.date.accessioned | 2024-12-24T19:23:58Z | |
| dc.date.available | 2024-12-24T19:23:58Z | |
| dc.date.issued | 2020 | |
| dc.department | Siirt Üniversitesi | |
| dc.description | 4th International Hydrogen Technologies Congress (IHTEC) -- JUN 20-23, 2019 -- Trakya Univ, Edirne, TURKEY | |
| dc.description.abstract | This study presents 4,40-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H-2 generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H-2 generation rates were calculated as 952.5 mmol H-2/g(cat). min and 614.4 mmol H-2/g(cat). min at 50 degrees C and 30 degrees C respectively for sodium borohydride hydrolysis reaction. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. | |
| dc.identifier.doi | 10.1016/j.ijhydene.2020.07.156 | |
| dc.identifier.endpage | 34792 | |
| dc.identifier.issn | 0360-3199 | |
| dc.identifier.issn | 1879-3487 | |
| dc.identifier.issue | 60 | |
| dc.identifier.scopus | 2-s2.0-85089294589 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 34783 | |
| dc.identifier.uri | https://doi.org/10.1016/j.ijhydene.2020.07.156 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12604/5793 | |
| dc.identifier.volume | 45 | |
| dc.identifier.wos | WOS:000609161600021 | |
| dc.identifier.wosquality | Q2 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | |
| dc.publisher | Pergamon-Elsevier Science Ltd | |
| dc.relation.ispartof | International Journal of Hydrogen Energy | |
| dc.relation.publicationcategory | Konferans Öğesi - Uluslararası - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.snmz | KA_20241222 | |
| dc.subject | Sodium borohydride | |
| dc.subject | Catalyst | |
| dc.subject | Schiff base | |
| dc.subject | Hydrolysis | |
| dc.title | Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction | |
| dc.type | Conference Object |
