Metallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties

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dc.authoridDUNDAR, ABDURRAHMAN/0000-0002-7930-1054
dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorDede, Emrah
dc.contributor.authorGumus, Selcuk
dc.contributor.authorDundar, Abdurrahman
dc.contributor.authorOkumus, Veysi
dc.date.accessioned2024-12-24T19:24:23Z
dc.date.available2024-12-24T19:24:23Z
dc.date.issued2014
dc.departmentSiirt Üniversitesi
dc.description.abstractA novel phthalonitrile derivative bearing 2-isopropyl-6-methylpyrimidin-4-yloxy substituents at peripheral positions was synthesized by a nucleophilic substitution reaction. Metallophthalocyanines were obtained from the reaction of the novel phthalonitrile with metal Zn, Cu, Co, and Ni salts. The characterization of the compounds was performed using elemental analysis as well as UV/Vis, FT-IR, and H-1-NMR spectroscopy. The aggregation behaviors of phthalocyanine complexes were also investigated. These metallophthalocyanines do not show any aggregation behavior between 10 (4)-10 (6) M concentration range in THF. The antioxidant activities of the synthesized compounds were evaluated using three different tests: 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, metal chelating activity, and reducing power assays. All the compounds exhibited various antioxidant activities. In addition, antimicrobial activity of the compounds was tested over four gram positive and two gram negative bacteria. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6-31G(d,p) level in order to obtain information about the 3D arrangements and electronic structure.
dc.identifier.doi10.1002/zaac.201400129
dc.identifier.endpage1959
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85117547797
dc.identifier.scopusqualityQ3
dc.identifier.startpage1953
dc.identifier.urihttps://doi.org/10.1002/zaac.201400129
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5954
dc.identifier.volume640
dc.identifier.wosWOS:000340900200015
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPhthalocyanines
dc.subjectCharacterization
dc.subjectAggregation
dc.subjectAntioxidant activity
dc.subjectAntibacterial activity
dc.subjectElectronic structure
dc.titleMetallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties
dc.typeArticle

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