The effect of spatial distribution of Zn vacancies in ZnS quantum dots on optical absorption spectra

dc.contributor.authorPimachev, Artem
dc.contributor.authorProshchenko, Vitaly
dc.contributor.authorHoroz, Sabit
dc.contributor.authorSahin, Omer
dc.contributor.authorDahnovsky, Yuri
dc.date.accessioned2017-05-03T11:31:04Z
dc.date.available2017-05-03T11:31:04Z
dc.date.issued2017-04-05
dc.departmentBelirleneceken_US
dc.description.abstractIn this work we propose how to identify the location and spatial distribution of Zn vacancies in ZnS quantum dots (QDs). The experiments reveal a peak shift in absorption spectra towards the lower energies (about 0.1 eV) in the presence of Zn vacancies. To explain such a shift we computationally study the absorption spectra when Zn vacancies are localized in the core, on the surface, and both in the core and on the surface of a quantum dot. From the comparison with the experimental data we conclude that the most favorable configuration of the vacancies is an aggregation on a QD surface. We find that Zn vacancies localized in the core or uniformly distributed on the QD surface, do not explain the experimentally observed shift in the absorption curves.en_US
dc.description.provenanceSubmitted by Sabit HOROZ (sabithoroz@siirt.edu.tr) on 2017-05-03T11:31:04Z No. of bitstreams: 1 Solid state communications.pdf: 760439 bytes, checksum: aa391fa1ce643d361c8cd5a354b13b9b (MD5)en
dc.description.provenanceMade available in DSpace on 2017-05-03T11:31:04Z (GMT). No. of bitstreams: 1 Solid state communications.pdf: 760439 bytes, checksum: aa391fa1ce643d361c8cd5a354b13b9b (MD5) Previous issue date: 2017-04-05en
dc.description.sponsorshipThis work was supported by a grant (No. DEFG02-10ER46728) from the Department of Energy to the University of Wyoming.en_US
dc.identifier.issn0038-1098
dc.identifier.scopus2-s2.0-85017444583
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://hdl.handle.net/20.500.12604/453
dc.identifier.wosWOS:000401101400010
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.relation.ispartofseriesSolid State Communications;doi.org/10.1016/j.ssc.2017.04.004
dc.relation.publicationcategoryUlusal Hakemli Dergi Makalesien_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKG_20241224
dc.titleThe effect of spatial distribution of Zn vacancies in ZnS quantum dots on optical absorption spectraen_US
dc.typeArticleen_US

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