Dynamic 1H NMR Studies of Schiff Base Derivatives

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dc.authoridtemel, hamdi/0000-0001-9225-7425
dc.contributor.authorKoylu, M. Z.
dc.contributor.authorEkinci, A.
dc.contributor.authorBoyukata, M.
dc.contributor.authorTemel, H.
dc.date.accessioned2024-12-24T19:24:37Z
dc.date.available2024-12-24T19:24:37Z
dc.date.issued2016
dc.departmentSiirt Üniversitesi
dc.description.abstractThe spin-lattice relaxation time T (1) and the spin-spin relaxation time T (2) of two Schiff base derivatives, N,N'-ethylenebis(salicylidene)-1,2-diaminoethane (H2L1) and N,N'-ethylenebis (salicylidene)-1,3-diaminopropane (H2L2), in DMSO-d(6) solvent were studied as a function of temperature in the range of 20-50A degrees C using a Bruker Avance 400.132 MHz H-1 NMR spectrometer. Based on the activation energy (E (a)) and correlation time (tau(c)), we believe that the Schiff base derivatives perform a molecular tumbling motion.
dc.description.sponsorshipresearch foundation of Dicle University [DUBAP-09-FF-30]
dc.description.sponsorshipThis work was supported by the research foundation of Dicle University (grant DUBAP-09-FF-30).
dc.identifier.doi10.1007/s10812-016-0202-8
dc.identifier.endpage909
dc.identifier.issn0021-9037
dc.identifier.issn1573-8647
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84954557964
dc.identifier.scopusqualityQ4
dc.identifier.startpage905
dc.identifier.urihttps://doi.org/10.1007/s10812-016-0202-8
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6057
dc.identifier.volume82
dc.identifier.wosWOS:000368717100003
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Applied Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectNMR
dc.subjectSchiff base
dc.subjectT-1 and T-2 relaxation time
dc.subjectactivation energy
dc.subjectcorrelation time
dc.titleDynamic 1H NMR Studies of Schiff Base Derivatives
dc.typeArticle

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