Synthesis and Spectral Studies of Macrocyclic Pb(II), Zn(II), Cd(II) and La(III) Complexes by Template Reaction of 1,2-Bis(2-formylphenyl)ethane with Metal Nitrate and Various Diamine

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dc.authoridtemel, hamdi/0000-0001-9225-7425
dc.authoridTEGIN, IBRAHIM/0000-0002-5661-7195
dc.authoridPasa, Salih/0000-0002-4792-8821
dc.authoridIlhan, Salih/0000-0003-0779-2744
dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorPasa, Salih
dc.contributor.authorTegin, Ibrahim
dc.date.accessioned2024-12-24T19:29:38Z
dc.date.available2024-12-24T19:29:38Z
dc.date.issued2010
dc.departmentSiirt Üniversitesi
dc.description.abstractEight new macrocyclic complexes were synthesized by template reaction of 1,4-bis(3-aminopropoxy)butane or (+/-)-trans-1,2-diaminocyclohexane with metal nitrate and 1,2-bis(2-formylphenyl)ethane and their structures were proposed on the basis of elemental analysis, FT-IR, UV-Vis, molar conductivity measurements, H-1 NMR and mass spectra. The metals to ligand molar ratios of the complexes were found to be 1 : 1. The complexes are 1 : 2 electrolytes for Cd(II), Pb(II) and Zn(II) complexes and 1 : 3 electrolytes for La(III) as shown by their molar conductivities (Lambda(m)) in DMSO at 10(-3) mol L-1. Due to the existence of free ions in these complexes, such complexes are electrically conductive. The configurations of Cd(II) and Zn(II) complexes were proposed to probably tetrahedral, La(III) complexes are octahedral and Pb(II) complexes are octahedral geometry in the L-1 complex and tetrahedral geometry in the L-2 complex.
dc.identifier.doi10.1134/S0036023610090111
dc.identifier.endpage1409
dc.identifier.issn0036-0236
dc.identifier.issn1531-8613
dc.identifier.issue9
dc.identifier.scopus2-s2.0-77957855669
dc.identifier.scopusqualityQ2
dc.identifier.startpage1402
dc.identifier.urihttps://doi.org/10.1134/S0036023610090111
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7178
dc.identifier.volume55
dc.identifier.wosWOS:000283092800011
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofRussian Journal of Inorganic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.titleSynthesis and Spectral Studies of Macrocyclic Pb(II), Zn(II), Cd(II) and La(III) Complexes by Template Reaction of 1,2-Bis(2-formylphenyl)ethane with Metal Nitrate and Various Diamine
dc.typeArticle

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