Hydrogen production from NaBH4 using Co-Cu-B catalysts prepared in methanol: Effect of plasma treatment

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dc.authoridIZGI, Mehmet Sait/0000-0003-3685-3219
dc.authoridSAKA, Cafer/0000-0003-2534-5921
dc.authoridSAHIN, Omer/0000-0003-4575-3762
dc.contributor.authorIzgi, M. Sait
dc.contributor.authorSahin, Omer
dc.contributor.authorSaka, Cafer
dc.date.accessioned2024-12-24T19:27:14Z
dc.date.available2024-12-24T19:27:14Z
dc.date.issued2016
dc.departmentSiirt Üniversitesi
dc.description.abstractIn this work, methanol is used as an alternative to water. Preparation and characterization of Co-Cu-B catalysts in methanol for hydrogen generation from catalytic hydrolysis of sodium borohydride are studied. In addition, the plasma treated Co-Cu-B catalyst prepared in methanol for the hydrogen generation from catalytic hydrolysis of sodium borohydride is investigated. Process parameters including plasma gases, plasma time, NaOH and sodium borohydride concentrations and reaction temperature affecting the hydrolysis reaction of sodium borohydride in the presence of plasma treated Co-Cu-B catalysts are investigated. The maximum hydrogen generation rates of Co-Cu-B catalysts in water and methanol toward sodium borohydride hydrolysis are 734.4 and 3998 mL/g/min, respectively. Cold plasma treated Co-Cu-B catalyst for sodium borohydride hydrolysis is exhibited a hydrogen generation rate of about 4972 mL/g/min. The activation energy of the catalytic hydrolysis reaction of sodium borohydride with the plasma treated Co-Cu-B catalyst for first-order of is found at 17.38 kJ/mol. Copyright (c) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.ijhydene.2015.11.004
dc.identifier.endpage1608
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue3
dc.identifier.scopus2-s2.0-84954558772
dc.identifier.scopusqualityQ1
dc.identifier.startpage1600
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2015.11.004
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6541
dc.identifier.volume41
dc.identifier.wosWOS:000369461500025
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectCold plasma
dc.subjectSodium borohydride
dc.subjectMethanol
dc.subjectCo-Cu-B catalysts
dc.subjectHydrogen generation
dc.titleHydrogen production from NaBH4 using Co-Cu-B catalysts prepared in methanol: Effect of plasma treatment
dc.typeArticle

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