Selective preconcentration of Lanthanum(III) by Coriolus versicolor immobilised on Amberlite XAD-4 and its determination by ICP-OES

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dc.authoridDUNDAR, ABDURRAHMAN/0000-0002-7930-1054
dc.authoridOkumus, Veysi/0000-0002-5505-2700
dc.authoridKilinc, Ersin/0000-0001-5223-9919
dc.contributor.authorOzdemir, Sadin
dc.contributor.authorOkumus, Veysi
dc.contributor.authorDundar, Abdurrahman
dc.contributor.authorCelik, Kadir Serdar
dc.contributor.authorYuksel, Uyan
dc.contributor.authorKilinc, Ersin
dc.date.accessioned2024-12-24T19:28:06Z
dc.date.available2024-12-24T19:28:06Z
dc.date.issued2014
dc.departmentSiirt Üniversitesi
dc.description.abstractCoriolus versicolor, a wood fungus, was immobilised on Amberlite XAD-4 and used as solid-phase biosorbent for preconcentrations of rare earth elements. La(III), Th(IV), U(IV) and Ce(III) were subjected to solid-phase extraction procedure. We observed that La(III) was selectively preconcentrated, while other ions remained in solution at pH 6.0. 5.0mL of 1.0molL(-1) HCl was used to elaute La(III) from column. 250mg of C. versicolor loaded on 1000mg of XAD-4 was optimised as solid-phase matrix. Concentrations of ions in solutions were determined by inductively coupled plasma- optical emission spectrometry (ICP-OES). The calibration plot after preconcentration was linear in the range from 1.0 to 50.0ngmL(-1) for La(III). Limit of detection was found as 0.27ngmL(-1) for La(III) by SPE method. Relative standard deviation was found lower than 6.7% for 1.0ngmL(-1) of La(III) solution (n=10). The sensitivity of ICP-OES was improved by a factor of 46.8. The applicability of the method was validated through the analysis of certified reference samples of tea (NCS ZC-73014) and spinach (NCS ZC-73013).
dc.identifier.doi10.1080/03067319.2013.831412
dc.identifier.endpage545
dc.identifier.issn0306-7319
dc.identifier.issn1029-0397
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84897398053
dc.identifier.scopusqualityQ1
dc.identifier.startpage533
dc.identifier.urihttps://doi.org/10.1080/03067319.2013.831412
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6924
dc.identifier.volume94
dc.identifier.wosWOS:000334065100001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofInternational Journal of Environmental Analytical Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectLanthanum
dc.subjectrare earth elements
dc.subjectsolid-phase extraction
dc.subjectselective preconcentration
dc.subjectCoriolus versicolor
dc.titleSelective preconcentration of Lanthanum(III) by Coriolus versicolor immobilised on Amberlite XAD-4 and its determination by ICP-OES
dc.typeArticle

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