High volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst

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dc.contributor.authorKilinc, Dilek
dc.contributor.authorSahin, Omer
dc.date.accessioned2024-12-24T19:27:34Z
dc.date.available2024-12-24T19:27:34Z
dc.date.issued2020
dc.departmentSiirt Üniversitesi
dc.description.abstractIn this work, we aimed to present an efficient catalyst in potassium borohydride hydrolysis for hydrogen production. Therefore 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Pd complex was synthesized. FT-IR, SEM, TEM, BET, XRD, Elemental Analysis techniques was employed for characterization of Pd-complex catalyst. When the catalyst tested in KBH4 hydrolysis reaction, some affecting factors were studied such as temperatures (20 degrees C-50 degrees C), catalyst amounts (5-50 mg), KOH concentrations (0-10%) and KBH4 concentration (2-10%) The results displayed that the synthesized Palladium Schiff Base complex catalyst facilitates potassium borohydride hydrolysis with 25.194 kj/mol activation energy (Ea). Additionally, Pd Schiff Base complex demonstrated remarkable reusability performance and conserved 95% of its inherent catalytic activity even at sixth recycle. (C) 2020 Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.renene.2020.06.035
dc.identifier.endpage264
dc.identifier.issn0960-1481
dc.identifier.scopus2-s2.0-85089159303
dc.identifier.scopusqualityQ1
dc.identifier.startpage257
dc.identifier.urihttps://doi.org/10.1016/j.renene.2020.06.035
dc.identifier.urihttps://hdl.handle.net/20.500.12604/6708
dc.identifier.volume161
dc.identifier.wosWOS:000573215800008
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofRenewable Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectPotassium borohydride
dc.subjectHydrogen evolution
dc.subjectPd-complex
dc.subjectCatalyst
dc.subjectHydrolysis
dc.titleHigh volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst
dc.typeArticle

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