Metal-Schiff Base complex catalyst in KBH4 hydrolysis reaction for hydrogen production

Basit Öğe Kaydı
dc.contributor.authorKilinc, Dilek
dc.contributor.authorSahin, Omer
dc.date.accessioned2024-12-24T19:23:58Z
dc.date.available2024-12-24T19:23:58Z
dc.date.issued2019
dc.departmentSiirt Üniversitesi
dc.description3rd International Hydrogen Technologies Congress (IHTEC) -- MAR 15-18, 2018 -- Alanya Alaaddin Keykubat Univ, TURKEY
dc.description.abstractIt is the first study to synthesize Co(II)-Schiff Base complex and to use it like a catalyst for potassium borohydride hydrolysis reaction to hydrogen production. Co(II)-complex is synthesized with CoCl2 center dot 6H(2)O and 5-Amino-2,4-dichlorophenol-3,5-di-tert-butylsalisylaldimine ligand. KBH4 hydrolysis reaction is studied according as percentage of KBH4, percentage of KOH, amount of Co-Schiff Base complex catalyst and temperature effects. Co Schiff Base complex is highly effective catalyst and initial rates (R-o) of KBH4 hydrolysis reaction were 61220.00 and 99746.67 mL H-2. g(-1) cat. min(-1) at 30 degrees C and 50 degrees C. Furthermore this study includes the kinetic calculations and for this reaction calculated activation energy is 17.56 kJ mol(-1). (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.ijhydene.2019.01.229
dc.identifier.endpage18857
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue34
dc.identifier.scopus2-s2.0-85061634539
dc.identifier.scopusqualityQ1
dc.identifier.startpage18848
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2019.01.229
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5785
dc.identifier.volume44
dc.identifier.wosWOS:000477092000021
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectKBH4
dc.subjectComplex
dc.subjectHydrogen generation
dc.subjectCatalyst
dc.titleMetal-Schiff Base complex catalyst in KBH4 hydrolysis reaction for hydrogen production
dc.typeConference Object

Dosyalar

Koleksiyon

WOS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu