The effect of microwave irradiation on a Co-B-based catalyst for hydrogen generation by hydrolysis of NaBH4 solution
[ X ]
Tarih
2015
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Bellwether Publishing, Ltd.
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A Co-B-based catalyst was prepared under microwave irradiation for hydrogen generation by hydrolysis of NaBH4 solution. The activity of Co-B catalyst for hydrogen generation was studied in comparison with another Co-B catalyst prepared by the known methods. The results show that Co-B catalyst reduced prepared under microwave irradiation was quick and was completed in only 17 min, while the Co-B catalyst produced in a known method was slow and was completed in 27 min. The hydrogen generation from the hydrolys of NaBH4 with Co-B catalyst was investigated depending on NaBH4 and NaOH concentrations in solution, temperature, microwave applying time, and microwave applying power. Hydrolysis kinetics of NaBH4 were investigated at a temperature range of 30-50°C and zero-order kinetics were applied to the obtained data. Copyright © Taylor & Francis Group, LLC.
Açıklama
Anahtar Kelimeler
Co-B catalyst, hydrogen generation, kinetic, microwave irradiation, sodium borohydride
Kaynak
Energy Sources, Part A: Recovery, Utilization and Environmental Effects
WoS Q Değeri
Scopus Q Değeri
Q1
Cilt
37
Sayı
5
