Al2O3 SUPPORTED Co-Cu-B (Co-Cu-B/Al2O3) CATALYST FOR HYDROGEN GENERATION BY HYDROLYSIS OF AQUEOUS SODIUM BOROHYDRIDE (NaBH4) SOLUTIONS

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dc.contributor.authorBaytar, O.
dc.contributor.authorIzgi, M. S.
dc.contributor.authorHoroz, S.
dc.contributor.authorSahin, O.
dc.contributor.authorNar, S.
dc.date.accessioned2024-12-24T19:33:08Z
dc.date.available2024-12-24T19:33:08Z
dc.date.issued2019
dc.departmentSiirt Üniversitesi
dc.description.abstractIn this study, Al2O3 supported Co-Cu-B (Co-Cu-B/Al2O3) catalyst was synthesized by chemical impregnation and precipitation method to be used for catalytic hydrogen generation from NaBH4. Co-Cu-B/Al2O3 catalyst was synthesized at various ratios using Co-Cu-B/Al2O3 (5-20%). The effect of some parameters such as NaOH concentration (0-7%), NaBH4 concentration (2.5-7.5%), catalyst amount (25-150 mg) and solution ambient temperature was investigated on the catalytic hydrolysis of NaBH4 . The hydrogen generation rate was found as 2519 and 8962 mL*g(-1)*min(-1) for Co-Cu-B and Co-CuB/Al2O3 catalysts in NaBH4 hydrolysis, respectively. The order rate kinetics and activation energy for Co-Cu-B/Al2O3 catalyst were determined as 0.125 and 27 kJ*mol(-1), respectively. The obtained results suggest that Co-Cu-B/Al2O3 catalysts can be used for mobile applications of PEMFC systems.
dc.identifier.endpage681
dc.identifier.issn1842-3582
dc.identifier.issue3
dc.identifier.startpage673
dc.identifier.urihttps://hdl.handle.net/20.500.12604/7973
dc.identifier.volume14
dc.identifier.wosWOS:000482729500018
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherInst Materials Physics
dc.relation.ispartofDigest Journal of Nanomaterials and Biostructures
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectActivation energy
dc.subjectCatalyst
dc.subjectCharacterization
dc.subjectHydrolysis
dc.subjectSynthesis
dc.titleAl2O3 SUPPORTED Co-Cu-B (Co-Cu-B/Al2O3) CATALYST FOR HYDROGEN GENERATION BY HYDROLYSIS OF AQUEOUS SODIUM BOROHYDRIDE (NaBH4) SOLUTIONS
dc.typeArticle

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