SYNTHESIS OF NOVEL BIS(PHOSPHINO)AMINE-RUII(ACAC)2 COMPLEXES, AND INVESTIGATION OF CATALYTIC ACTIVITY IN TRANSFER HYDROGENATION

dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorIşık, Uğur
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorBaysal, Akın
dc.date.accessioned2024-12-24T19:18:16Z
dc.date.available2024-12-24T19:18:16Z
dc.date.issued2022
dc.departmentSiirt Üniversitesi
dc.description.abstractIn this study, reactions of (PPh2)2NCH2CH2N(PPh2)2 (L1) and {(PPh2)2NCH2CH2}3N (L2) with [RuII(acac)2(CH3CN)2] led to the production of new dinuclear complex [Ru(acac)2]2(L1) (1) and trinuclear complex [Ru(acac)2]3(L2) (2). Complex 1 and 2 are excellent candidates for the role of catalyst precursors in the transfer hydrogenation (TH) of acetophenone and its derivatives. Compared to complex (1), the trinuclear complex (2) is an exceptional catalyst, producing the corresponding alcohols in 98–99% yields in 20 minutes at 80 oC (TOF?300 h-1 ) for the TH process. A comparison of the catalytic properties of the complexes is also briefly discussed. Complex structures have also been characterized by combining nuclear magnetic resonance (NMR), Fourier Transform Infrared (FT-IR), and elemental analysis.
dc.identifier.doi10.51477/mejs.1180235
dc.identifier.endpage156
dc.identifier.issn2618-6136
dc.identifier.issue2
dc.identifier.startpage147
dc.identifier.trdizinid1147729
dc.identifier.urihttps://doi.org/10.51477/mejs.1180235
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/1147729
dc.identifier.urihttps://hdl.handle.net/20.500.12604/5034
dc.identifier.volume8
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofMiddle East Journal of Science
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241222
dc.subjectRuthenium Complex
dc.subjectTransfer Hydrogenation
dc.subjectAminophosphine
dc.subjectHomogeneous Catalysis.
dc.titleSYNTHESIS OF NOVEL BIS(PHOSPHINO)AMINE-RUII(ACAC)2 COMPLEXES, AND INVESTIGATION OF CATALYTIC ACTIVITY IN TRANSFER HYDROGENATION
dc.typeArticle

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