Hydrogen generation from NaBH 4 solution with the high-performance Co(0) catalyst using a cold plasma method

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dc.contributor.authorŞahin, Ö.
dc.contributor.authorHansu, F.
dc.contributor.authorSaka, C.
dc.contributor.authorBaytar, O.
dc.date.accessioned2024-12-24T19:10:03Z
dc.date.available2024-12-24T19:10:03Z
dc.date.issued2014
dc.departmentSiirt Üniversitesi
dc.description.abstractThe hydrogen production from the hydrolysis of NaBH4 with Co(0) catalyst, which is prepared with a cold plasma method under nitrogen atmosphere, was investigated with effects of NaBH4 and NaOH concentration, temperature, plasma applying time and applying power, and Co(0) catalyst effect. The hydrolysis reaction completed within around 10-min time intervals with cold plasma, while the hydrolysis reaction in the known method completed within around 20-min time intervals. The completion rate of hydrolysis reaction with Co(0) catalyst in cold plasma media compared to non-plasma media increased to be around 100%. The yield of hydrogen in the presence of 3.2, 10, and 25% NaBH4 solution takes the values of around 94, 90, and 15% at the end of 600 sec, respectively. The experimental data were fitted to first-order. The activation energy for first-order was found to be 26.02 kJ mol-1. © 2014 Taylor & Francis Group,LLC.
dc.identifier.doi10.1080/15567036.2011.555443
dc.identifier.endpage1587
dc.identifier.issn1556-7036
dc.identifier.issue14
dc.identifier.scopus2-s2.0-84901424775
dc.identifier.scopusqualityQ1
dc.identifier.startpage1578
dc.identifier.urihttps://doi.org10.1080/15567036.2011.555443
dc.identifier.urihttps://hdl.handle.net/20.500.12604/3922
dc.identifier.volume36
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor and Francis Inc.
dc.relation.ispartofEnergy Sources, Part A: Recovery, Utilization and Environmental Effects
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241222
dc.subjectCo(0) catalyst
dc.subjectcold plasma
dc.subjecthydrogen generation
dc.subjectkinetic study
dc.subjectsodium borohydride
dc.titleHydrogen generation from NaBH 4 solution with the high-performance Co(0) catalyst using a cold plasma method
dc.typeArticle

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