Selective separation of cobalt using a new Co(II)-imprinted polymer/cryogel system

dc.authoridhttps://orcid.org/0000-0002-8014-7760en_US
dc.contributor.authorCanpolat, Gurbet
dc.date.accessioned2019-12-30T06:44:15Z
dc.date.available2019-12-30T06:44:15Z
dc.date.issued2018en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstractThe aim of the present study was to investigate selective separation and preconcentration of Co(II) ions in aqueous solutions by ion imprinted technique. For this purpose, Co(II)-methacryloylhistidine((MAH)2-Co(II)) complex monomer has been synthesized and polymerized with presence of 2-hydroxyethyl methacrylate (HEMA) followed by flushed out of bonded Co(II) ions from polymer with 5.0 mol*L-1 HNO3. Thus, specific cavities for re-binding of target ions (Co(II)) have been created onto p-HEMA-MAH cryogel column. Prepared metal complex and Co-imprinted polymer/cryogel system have been characterized by FTIR and SEM. The effect of various parameters such as pH, initial concentration, flow rate, ionic strength have been investigated to determine optimal adsorption conditions. The maximum amount of adsorbed Co(II) has found as 106.0 mg*g-1 at pH 8.0 with flow rate of 1 mL*min-1. For selectivity experiments, binding studies were carried out presence of Cu(II) and Ni(II). The k (selectivity coefficient) values have found as 8.9 and 3.8 for Co(II)/Cu(II) and Co(II)/Ni(II) binary mixture, respectively. The reuse of column also has been investigated and there was no significant decrease at adsorption capacity even in consecutive eleven experiments.en_US
dc.description.provenanceSubmitted by Gurbet Canpolat (gokalp.gurbet@siirt.edu.tr) on 2019-12-27T15:36:30Z No. of bitstreams: 1 10.17776-csj.455103-603584.pdf: 898797 bytes, checksum: 8e943b0fda537c32118e34fc34878546 (MD5)en
dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-30T06:44:15Z (GMT) No. of bitstreams: 1 10.17776-csj.455103-603584.pdf: 898797 bytes, checksum: 8e943b0fda537c32118e34fc34878546 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-30T06:44:15Z (GMT). No. of bitstreams: 1 10.17776-csj.455103-603584.pdf: 898797 bytes, checksum: 8e943b0fda537c32118e34fc34878546 (MD5) Previous issue date: 2018en
dc.identifier.citationCanpolat, G. Selective separation of cobalt using a new Co (II)-imprinted polymer/cryogel sdystem. Cumhuriyet Science Journal, 39(4), 920-927.en_US
dc.identifier.doi10.17776/csj.455103
dc.identifier.endpage927en_US
dc.identifier.issue4en_US
dc.identifier.startpage920en_US
dc.identifier.trdizinid319331
dc.identifier.urihttp://dx.doi.org/10.17776/csj.455103
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2558
dc.identifier.volume39en_US
dc.indekslendigikaynakTR-Dizin
dc.institutionauthorCanpolat, Gurbet
dc.language.isoenen_US
dc.relation.ispartofCumhuriyet Science Journal
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/restrictedAccessen_US
dc.snmzKG_20241224
dc.subjectIon Imprinted polymeren_US
dc.subjectcryogelen_US
dc.subjectcobalten_US
dc.subjectselective recognitionen_US
dc.titleSelective separation of cobalt using a new Co(II)-imprinted polymer/cryogel systemen_US
dc.title.alternativeYeni bir Co(II)-baskılı polimer/kriyojel sistem kullanılarak kobalt(II)'ın seçici olarak ayrılmasıen_US
dc.typeArticleen_US

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