Metallo phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy substituents: synthesis, characterization, aggregation behavior, antioxidant and antibacterial activity, and electronic properties.

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dc.authoridhttps://orcid.org/0000-0002-5505-2700en_US
dc.contributor.authorAğırtaş, Salih
dc.contributor.authorDede, Emrah
dc.contributor.authorGümüş, Selçuk
dc.contributor.authorDündar, Abdurrahman
dc.contributor.authorOkumuş, Veysi
dc.date.accessioned2019-12-25T07:39:18Z
dc.date.available2019-12-25T07:39:18Z
dc.date.issued2014en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstractA novel phthalonitrile derivative bearing 2-isopropyl-6- methylpyrimidin-4-yloxy substituents at peripheral positions was synthesized by a nucleophilic substitution reaction. Metallophthalocyanines were obtained from the reaction of the novel phthalonitrile with metal Zn, Cu, Co, and Ni salts. The characterization of the compounds was performed using elemental analysis as well as UV/Vis, FT-IR, and 1H-NMR spectroscopy. The aggregation behaviors of phthalocyanine complexes were also investigated. These metallophthalocyanines do not show any aggregation behavior between 10–4–10–6 M concentration range in THF. The antioxidant activities of the synthesized com-pounds were evaluated using three different tests: 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, metal chelating activity, and reducing power assays. All the compounds exhibited various antioxidant activities. In addition, antimicrobial activity of the compounds was tested over four gram positive and two gram negative bacteria. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6- 31G(d,p) level in order to obtain information about the 3D arrangements and electronic structure.en_US
dc.description.provenanceSubmitted by Veysi OKUMUŞ (veysiokumus@siirt.edu.tr) on 2019-12-23T16:42:42Z No. of bitstreams: 1 A22.pdf: 728230 bytes, checksum: e32b6c8ee892773536002b6cea0bf0b6 (MD5)en
dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-25T07:39:18Z (GMT) No. of bitstreams: 1 A22.pdf: 728230 bytes, checksum: e32b6c8ee892773536002b6cea0bf0b6 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-25T07:39:18Z (GMT). No. of bitstreams: 1 A22.pdf: 728230 bytes, checksum: e32b6c8ee892773536002b6cea0bf0b6 (MD5) Previous issue date: 2014en
dc.identifier.citationAğırtaş, M. S., Dede, E., Gümüş, S., Dündar, A., & Okumuş, V. (2014). Metallo Phthalocyanines bearing 2‐Isopropyl‐6‐methylpyrimidin‐4‐yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties. Zeitschrift für anorganische und allgemeine Chemie, 640(10), 1953-1959.en_US
dc.identifier.endpage1959en_US
dc.identifier.issue10en_US
dc.identifier.startpage1953en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2406
dc.identifier.volume640en_US
dc.institutionauthorOkumuş, Veysi
dc.language.isoenen_US
dc.publisherZeitschrift für und allgemeine Chemie.en_US
dc.relation.ispartofZeitschrift für anorganische und allgemeine Chemie.
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz#KayıtKontrol#
dc.subjectPhthalocyaninesen_US
dc.subjectCharacterizationen_US
dc.subjectAggregationen_US
dc.subjectAntioxidant activityen_US
dc.subjectAntibacterial activityen_US
dc.subjectElectronic structureen_US
dc.titleMetallo phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy substituents: synthesis, characterization, aggregation behavior, antioxidant and antibacterial activity, and electronic properties.en_US
dc.typeArticleen_US

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